Full silicidation ͑FUSI͒ of polysilicon gates promises to be a simple approach for formation of metal gate electrodes for highly scaled complementary metal oxide semiconductor ͑CMOS͒ transistors. Devices have been reported with several different silicides, prominently with nickel. NiSi was shown to produce different work functions, covering a large portion of silicon bandgap, in relation to a dopant type and amount present in polysilicon. Elimination of polysilicon gate electrode depletion has been demonstrated. Data indicates that significant reduction of gate tunneling current is possible. A summary of developments of this new approach to metal gates and discussion of issues and challenges of the FUSI process and its applicability to highly scaled technologies is presented.Metal gates were a mainstay of metal oxide semiconductor ͑MOS͒ integrated circuits for many years until the need for denserpacked circuits brought about an end to aluminum gates and introduced a self-aligned approach afforded by polysilicon gate electrodes. Today, a comeback of metal gates is forecast in highperformance devices. Such gate electrodes deliver advantages of:No boron penetration from the polysilicon gate into channels through very thin gate dielectric, an increasingly difficult condition to maintain as gate dielectrics become thinner in scaled devices. Alternatively, a successful introduction of high-k dielectric could relax this constraint.Much lower gate resistance. Gate resistance-capacitance ͑RC͒ delay becomes a significant concern in designing circuits with very short gates.Desirable work function ͑WF͒ setting. Unlike polysilicon electrodes which have only two WFs available, one for n-channel MOS ͑n-MOS͒ and one for p-channel MOS ͑p-MOS͒, metal electrodes can set almost any WF for these devices. Specifically, a range of WFs from ϳ4.1 − 4.4 and ϳ4.8 − 5.1 eV would be attractive for n-MOS and p-MOS, respectively, for bulk and partially depleted silicon-on-insulator ͑PD SOI͒ transistors, and a range of WFs spanning almost the entire silicon bandgap could be utilized in fully depleted ͑FD SOI͒ devices, including FinFETs and Tri-gates.Perhaps the most desirable advantage of reduced electrical thickness of the gate dielectric ͑CET͒. Metal gates can fully eliminate depletion in heavily doped polysilicon gates ͑present in high vertical fields͒, which can amount to a 3-5 Å reduction in CET, the equivalent of a ϳtwo generation advancement.Metal gates have been realized in two general approaches: gatefirst and gate-last. The former approach retains the order of standard polysilicon gate process flow. Its main disadvantages are concerns about contamination of front-end tools during processing, particularly furnaces, difficult metal etching, and integrity of gate stack during high-temperature annealing. The gate-last approach is also called a replacement gate technique, where a dummy gate is removed after all doping and high-temperature processes are completed. Its main challenge is the dummy gate stack removal and replacement. Table I s...