High Modulus and High Strength Fibers with High Electric Conductivity Prepared by Copper Electroless Plating on the Surface of Poly(p-phenylenebenzobisoxazole) (PBO)

Matsuo, Masaru; Ishikawa, Hisako; Xiang, Ying; Bin, Yuezhen

doi:10.1295/polymj.pj2006161

Cited by 3 publications

(5 citation statements)

References 22 publications

(18 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Since polymer fibres are non-conductors of electricity, this method was resorted to for metallizing the polymer fibres to improve the wettability of the fibres with the metal matrix for the development of HPP reinforced MMC. It was already reported [6,8] that PBO fibres can be electroless copper coated, and that copper is the most suitable material that has very good adhesion with the PBO fibres when compared with other materials like nickel, silver, and gold. Copper metal also has higher melting point of 1358.15 K, which is much higher than the processing temperature of the metal matrix materials considered here, and also forms chemical compounds with that of suitable matrix materials which can be inferred with the help of phase diagrams.…”

Section: Electroless Coatingmentioning

confidence: 98%

“…The PBO fibres were pre-treated before the actual electroless copper coating process [8]. This pre-treatment prepares the surface of the polymer fibres for electroless copper coating.…”

Section: Pre-treatment Of Pbo Fibresmentioning

confidence: 99%

“…The surface activated PBO fibres from the pre-treatment were immersed in an electroless copper coating bath solution containing copper sulphate-penta-hydrate, sodium salt of ethylenediamine-tetraacetic-acid, formaldehyde, sodium sulphate, sodium acetate, and Potassium Cyanide, for 30 min at 303.15 K, in basic pH range, maintained by ammonia buffer [8]. From the prepared electroless copper coating bath solution the copper ions present in the electrolyte solution get coated on the activated PBO polymer fibres as metal copper.…”

Section: Copper Coating Of Pbo Fibresmentioning

confidence: 99%

See 2 more Smart Citations

High Performance Polymer Fibre-Metal Matrix Composites of Metal-Organic Frameworks - Metallization, Processing, Properties and Applications

2019

Metal-Organic Framework Composites - Volume I

View full text Add to dashboard Cite

Metal-Organic Frameworks (MOFs) are increasingly being applied in space, automotive, electronic and aerospace applications. In this chapter, high performance engineering polymeric fibres are demonstrated to not only reinforce low melting metals and alloys due to their superior mechanical properties, high thermal resistance up to about 650 °C and resistance to corrosive environment but also light weight resulting composites by reducing the densities. High-performance polymer fibres have superior mechanical properties like specific strength and stiffness that enable them for structural applications. Though high-performance polymer fibres like Kevlar and Zylon were developed two to three decades back, they were still not used as a reinforcement in metal matrix composites, but were used only with other polymer matrices, which generally have good wettability and low processing temperature which are sufficiently low enough not to degrade the reinforcing polymers but also provide cost effective product level solutions with superior performance. Some of the reasons for not using high-performance polymer fibres as a potential reinforcement in metallic materials are their low wettability, poor interfacial properties, and low degradation or heat distortion temperatures in relation to the metal matrix, when processed by conventional manufacturing processes. This chapter presents techniques of metallizing the high-performance polymer fibre surfaces for compatibility with the metallic matrices, using techniques such as electroless coatings, Radio Frequency (RF) ion sputtering and High Velocity Oxygen Fuel (HVOF) thermal spray processes. The metallic coatings improve the wettability of the polymer fibre with the metal matrix and protect the fibre from high thermal gradients that arise during

show abstract

Section: Electroless Coatingmentioning

confidence: 98%

“…The PBO fibres were pre-treated before the actual electroless copper coating process [8]. This pre-treatment prepares the surface of the polymer fibres for electroless copper coating.…”

Section: Pre-treatment Of Pbo Fibresmentioning

confidence: 99%

Section: Copper Coating Of Pbo Fibresmentioning

confidence: 99%

See 1 more Smart Citation

High Performance Polymer Fibre-Metal Matrix Composites of Metal-Organic Frameworks - Metallization, Processing, Properties and Applications

2019

Metal-Organic Framework Composites - Volume I

View full text Add to dashboard Cite

show abstract

“…Alternative conditions of electroless deposition and metal types (e.g., Au, Pt, and Pd,) should be encouraged and moreover be explored to find the scope for formation of more stable metal over-layers with slight or without any metal atom penetration. Electroless Cu plating developed on nanofibers with the attributes of [67] high modulus and high strength, and particularly high electric conductivity on the surface of poly (p-) phenylene benzobisoxazole. A simple electroless Cu-coated prepared on glass nanofiber with excellent conductivity.…”

Section: Nanocharacteristics Of Electroless Coppermentioning

confidence: 99%

Electroless Deposition of Nanolayered Metallic Coatings

Sudagar¹,

Tamilarasan²,

Sanjith³

et al. 2017

Nanoscaled Films and Layers

View full text Add to dashboard Cite

Electroless metallic coating is referred as the deposition of a substrate material by the process of chemical or autocatalytic reduction of aqueous metal ions deposited to a substrate material without any external supply of power. Electroless nickel alloys are generally considered synonymous to the word "electroless coating" as ~90% of productions in industries are of this alloy coating. Rest of the electroless metallic coatings includes gold, copper, palladium, cobalt, silver, etc. These electroless metallic coatings (other than electroless nickel coatings) are also one of the vibrant areas in the field of materials properties and surface engineering research. From the year 2000 to till date, nearly 1000 SCI indexed research papers were published on this topic. However, no comprehensive studies about the recent progress on this topic were reported elsewhere so far. In this context, the present chapter aims to give a complete overview on various aspects of the rest of the electroless metallic nanocoatings/layer as a whole. More importance will be on the recent developments of the nanocharacteristics and future scopes.

show abstract

“…Nevertheless, the current copper wires become finer, the tensile-strength become weaker. To solve this problem, the production technique of copper wire, which is formed with copper plated on the surface of a super fiber, is researched [1]. Although the super fiber is a high strength and high modulus polymer resin, adhesion strength between the metal and the resin is weak due to low surface energy of the resin, and the copper plated layer on the resin is easily peeled off [2].…”

Section: Introductionmentioning

confidence: 99%

Improvement of the adhesion strength between copper plated layer and resin substrate using a chemically adsorbed monolayer

Tsuchiya

Ohtake

Ogawa

2013

MATEC Web of Conferences

View full text Add to dashboard Cite

Abstract. With reducing the size and weight of electric devices, high-tensile, light and fine copper wire is demanded. So the production technique of a copper wire plated on a super fiber resin (Vectran film) was researched for improving the adhesion strength between the copper and the resin. In this study, we used the Cu 2+ or Pd 2+ complex prepared with a chemically adsorbed monolayer (CAM) to improve the adhesion strength between the copper plated layer and the Vectran film. As the result of scotch tape test, it was observed that the adhesion strength between the copper plated layer and Vectran film was improved by the Cu 2+ or Pd 2+ complex CAM.

show abstract

High Modulus and High Strength Fibers with High Electric Conductivity Prepared by Copper Electroless Plating on the Surface of Poly(p-phenylenebenzobisoxazole) (PBO)

Cited by 3 publications

References 22 publications

High Performance Polymer Fibre-Metal Matrix Composites of Metal-Organic Frameworks - Metallization, Processing, Properties and Applications

High Performance Polymer Fibre-Metal Matrix Composites of Metal-Organic Frameworks - Metallization, Processing, Properties and Applications

Electroless Deposition of Nanolayered Metallic Coatings

Improvement of the adhesion strength between copper plated layer and resin substrate using a chemically adsorbed monolayer

Contact Info

Product

Resources

About