Titanium-Catalyzed Intermolecular Hydroaminoalkylation of ConjugatedDienes. -For the first time the new and highly atom-efficient reaction for the synthesis of homoallylic amines from readily available 1,3-butadienes is presented. The scope of the reaction is still limited [e.g. reaction of (If), (Vb), and (VIIIb)]. Aliphatic dienes (XI) react much more regioselectively than the aromatic ones. -(PREUSS, T.; SAAK, W.; DOYE*, S.; Chem. -Eur.