High Efficiency Membranes Based on PTMSP and Hyper-Crosslinked Polystyrene for Toxic Volatile Compounds Removal from Wastewater

Abstract

For the first time, membranes based on poly(1-trimethylsilyl-1-propyne) (PTMSP) with 5–50 wt% loading of hyper-crosslinked polystyrene sorbent particles (HCPS) were obtained; the membranes were investigated for the problem of effective removal of volatile organic compounds from aqueous solutions using vacuum pervaporation. The industrial HCPS sorbent Purolite Macronet™ MN200 was chosen due to its high sorption capacity for organic solvents. It has been found that the membranes are asymmetric when HCPS content is higher than 30 wt%; scanning electron microscopy of the cross-sections the membranes demonstrate that they have a clearly defined thin layer, consisting mainly of PTMSP, and a thick porous layer, consisting mainly of HCPS. The transport and separation characteristics of PTMSP membranes with different HCPS loading were studied during the pervaporation separation of binary and multicomponent mixtures of water with benzene, toluene and xylene. It was shown that the addition of HCPS up to 30 wt% not only increases the permeate fluxes by 4–7 times, but at the same time leads to 1.5–2 fold increase in the separation factor. It was possible to obtain separation factors exceeding 1000 for all studied mixtures at high permeate fluxes (0.5–1 kg/m2∙h) in pervaporation separation of binary solutions.

Aromatic volatile organic compounds absorption with phenyl‐based deep eutectic solvents: A molecular thermodynamics and dynamics study

“…Thus, it is urgent to treatment or eliminate aromatic VOCs for the purpose of both environmental protection and human health. At present, the treatment methods of VOCs can be divided into two categories: destructive methods (e.g., catalytic combustion, plasma, and biological oxidation), 10–15 and recovery methods (e.g., adsorption, absorption, and membrane separation) 16–22 . The most widely used of the former is catalytic combustion, which is essentially a redox reaction with the help of a catalyst to convert organic matter into CO 2 and water.…”

“…At present, the treatment methods of VOCs can be divided into two categories: destructive methods (e.g., catalytic combustion, plasma, and biological oxidation), [10][11][12][13][14][15] and recovery methods (e.g., adsorption, absorption, and membrane separation). [16][17][18][19][20][21][22] The most widely used of the former is catalytic combustion, which is essentially a redox reaction with the help of a catalyst to convert organic matter into CO 2 and water. The technology is limited the application for low-concentration and single-component VOC streams, the lifetime and selectivity of the catalyst is a challenge, and the additional CO 2 emissions are generated.…”