2022
DOI: 10.1016/j.jcis.2021.11.050
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High-efficiency (>20%) planar carbon-based perovskite solar cells through device configuration engineering

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Cited by 46 publications
(45 citation statements)
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“…As purging and venting the vacuum chamber requires large amounts of time and energy, the thermal evaporation of metal electrodes is difficult to scale up, and it is uncertain whether it would be commercially viable. The carbon-based back-contact, deposited as a carbon paste, could potentially remove the need of a hole transport layer (HTL). Despite this, the layer thickness of the carbon electrode is much higher than that required for metal electrodes (Table S3), mainly due to its lower conductivity, with the thickness reaching up to 60 μm for the most efficient devices . This means a much higher material requirement per m 2 of panel.…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…As purging and venting the vacuum chamber requires large amounts of time and energy, the thermal evaporation of metal electrodes is difficult to scale up, and it is uncertain whether it would be commercially viable. The carbon-based back-contact, deposited as a carbon paste, could potentially remove the need of a hole transport layer (HTL). Despite this, the layer thickness of the carbon electrode is much higher than that required for metal electrodes (Table S3), mainly due to its lower conductivity, with the thickness reaching up to 60 μm for the most efficient devices . This means a much higher material requirement per m 2 of panel.…”
Section: Resultsmentioning
confidence: 99%
“…13−15 Despite this, the layer thickness of the carbon electrode is much higher than that required for metal electrodes (Table S3), mainly due to its lower conductivity, with the thickness reaching up to 60 μm for the most efficient devices. 16 This means a much higher material requirement per m 2 of panel. Using an optimistic scenario of 2-μm thickness for the carbon layer, options 5 and 6 (Table 1) are the most expensive.…”
mentioning
confidence: 99%
“…[13] Since then, the carbon-electrode-based PSCs (C-PSCs) have attracted intensive research interest and have been widely reported. Over the past decade, through rational optimization of compositions, morphologies, processing techniques, contact junctions, and device architectures, the PCEs of C-PSCs have been progressively elevated to exceed 22%, [14][15][16] gradually diminishing the PCE gap with the metal CEs-based counterparts. And the operational stability of C-PSCs has been extended to nearly 10 000 h, significantly outperforming the metal CEs-based devices.…”
Section: Introductionmentioning
confidence: 99%
“…[ 21 ] Rational design and engineering of interface layers can play an essential role in further improving the performance and industrial viability of PSCs. [ 22–30 ]…”
Section: Introductionmentioning
confidence: 99%
“…[21] Rational design and engineering of interface layers can play an essential role in further improving the performance and industrial viability of PSCs. [22][23][24][25][26][27][28][29][30] So far, highly efficient PSCs have been mostly demonstrated for the n-i-p device configuration, with 2,2 0 ,7,7 0 -tetrakis(N,N-dip-methoxyphenylamine)-9,9 0 spirobifluorene (Spiro-MeOTAD) or poly(triarylamine) (PTAA) as the hole-transporting layer (HTL) and an ultrathin molecular layer, e.g., phenethylammonium iodide (PEAI), to passivate the perovskite top surface. [31][32][33] However, not all of these concepts are equally scalable.…”
Section: Introductionmentioning
confidence: 99%