The unique properties of the semiconductor material lnAsSb make it of interest for a variety of applications in the infrared. lnAsSb has the smallest bandgap of any of the standard III-V alloys (excluding those containing Bi and T1) with a value of 0.145 eV at 0 K for lnAso.37Sbo.63 (see Fig. 1). Because lnAsSb has the smallest bandgap of any III-V semiconductor, it may offer the limit in III-V device performance in terms of speed, long wavelength for optoelectronics, and quantum effects related to low effective mass. These properties, together with advances in III-V growth and processing technologies, have resulted in increased effort in research and development of InAsSb material and devices.The range of bandgap energies available in the lnAsSb ternary system make it suitable for use in midwave (3 to 6 J.lm) and far infrared (> 6 J.lID) devices. The bandgap and lattice constant for lnAsSb are shown in Fig. 1. Figure 1 is based on data obtained from material grown at high temperature, primarily from the melt or liquid phase [1]. There is a large variation of the lattice constant for InAsSb with composition, and the lattice constant is approximately linear with composition (Vegard's Law). For lnAsl-xSbx, the composition dependence of the bandgap at T= 0 K obeys an expression of the form of equation (1).Eg (1-x}The bandgap decrease between 0 K and 300 K is estimated as 60 meV throughout the InAsSb system. InAsSb has a zincblende crystal structure