“…For W' = À1, all the signs are reversed [Equation (5) However, the prompt dissociation may also proceed nonadiabatically, via a mechanism that involves an H atom spin flip. This occurs either through the a 3 P 1 state, which yields products in their electronic ground states, or through a second pathway, which leads to electronically (spin-orbit) excited Cl( 2 P 1/2 ) [henceforth referred to also as Cl*; see Equations (6) and (7) If either the spin-down channel [Equation (5)] or the spin-up channel [Equations (6) and (7)] dominates, then SPH will be produced. The degree of nascent SPH produced by the photodissociation must be probed before secondary collisions can cause relaxation, preferably using pulsed-laser detection.…”