“…As a result, higher filler concentrations are required in Ag NPs and polymer composites to achieve optimal TC. This is due to crystal defects and incomplete thermal conduction pathways formed during sintering. , However, increasing the filler rate can negatively impact the printability and cost-effectiveness of TCAs. To address these challenges, researchers have proposed two solutions: first, surface modification of the metal filler to reduce interfacial thermal resistance between the filler and polymer; second, hybridization with other thermally conductive fillers, such as graphene, expanded graphite, boron nitride nanosheets, and MXene, to strengthen the TC network. ,− Chen et al a “top-down” strategy by splitting highly purified Ag foil with nanoscale thickness was adopted to prepare two-dimensional Ag nanoflakes with an intrinsic thermal conductivity of 398.2 W/(m·K), reaching 93% of the theoretical value.…”