High accuracy pre-formed gradient discontinuous flow titrimetry

Petty, John D.; Petty, Denise A.; Peachey, Russell M.; Smith, Thomas K.; Krieger, Brian L.

doi:10.1016/0039-9140(94)80139-8

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The Discontinuous Flow Analyser1

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2012

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“…The feasibility of spectrophotometric determinations requiring reagent additions and spectrophotometric titrations was reported in relation to zinc and acidity determinations in electrolytic solutions [141]. Furthermore, a titrimetric procedure exploiting concentration gradients was proposed [142]: the sample travelled at a constant flow rate, being inserted by differential pumping into the carrier stream where a titrant concentration gradient had already been formed. In this way, ultrafast titrations (one titration every 25 s) were accomplished, yielding results comparable with classical titrations.…”

Section: The Discontinuous Flow Analysermentioning

confidence: 99%