2018
DOI: 10.1016/j.apsusc.2018.06.107
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Hierarchical Ni3S2-NiOOH hetero-nanocomposite grown on nickel foam as a noble-metal-free electrocatalyst for hydrogen evolution reaction in alkaline electrolyte

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Cited by 47 publications
(16 citation statements)
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“…Recently, Wang et al reported that amorphous Ni 3+ OOH electrodeposited on the Ni3S2@nickel foam exhibited synergistic effect for improving its electrocatalytic HER activity in 1 M NaOH electrolyte [20]. The Raman spectra of NiS compounds synthesized by 2h, 4h and 6h (Fig.…”
Section: Figmentioning
confidence: 98%
“…Recently, Wang et al reported that amorphous Ni 3+ OOH electrodeposited on the Ni3S2@nickel foam exhibited synergistic effect for improving its electrocatalytic HER activity in 1 M NaOH electrolyte [20]. The Raman spectra of NiS compounds synthesized by 2h, 4h and 6h (Fig.…”
Section: Figmentioning
confidence: 98%
“…The Tafel slope of sample NC-1/2 is 106 mV dec −1 , much lower than that of samples NM-0 (268 mV dec −1 ), NM-1/8 (181 mV dec −1 ), NM-1/4 (147 mV dec −1 ), and NM-1/2 (141 mV dec −1 ), suggesting its enhanced HER kinetics. 54,55 The Nyquist curves shown in Figure 6d indicate that sample NC-1/2 displays the smallest semicircle diameter than other samples, demonstrating a faster charge transfer rate, 56 but a slightly larger electrolyte resistance, which is related to the form of MgO with poor electrical conductivity (the content of MgO in the sample is 39.8 wt %; the calculation details are shown in the Supporting Information). Besides, electrochemically active surface areas (ECSA) estimated by C dl is also used to evaluate the HER activity of samples.…”
Section: Hydrogen Evolution Reaction Of the Electrocatalystsmentioning
confidence: 99%
“…). [28] The emergence of Ni 3 S 2 in the samples indicates that the surface of the nickel foam was transformed into Ni 3 S 2 by reaction with H 2 S, which was oriented from ammonium tetrathiomolybdate. [37] To identify the morphology of the product, the scanning electron microscope (SEM) image was recorded ( Figure 1-c).…”
Section: Resultsmentioning
confidence: 93%
“…[26] Its HER catalysis ability also needs to be further enhanced, however. Several attempts have been conducted to improve the catalysis efficiency by combination with other materials such as NiOOH, [27] Co (OH) 2 , [28] VS 2 , [29,30] Co 9 S 8 , [31] MoS 2 [32,33] or others. [34] All these efforts are beneficial to the enhancement of HER performances, but complex synthesis limits large production and industrial usage.…”
Section: Introductionmentioning
confidence: 99%