“…The characteristic diffraction peaks corresponding to tetragonal phase ZrO 2 (t-ZrO 2 ) (PDF#50-1089) and monoclinic phase ZrO 2 (m-ZrO 2 ) (PDF#83-0941) were found for all these six catalysts from the observed patterns. 39 The diffraction peaks at 2theta = 50° and 62° between ZnO and ZrO 2 were assigned to ZnZrO x solid solution, 23 indicating that the ZnZrO x solid solution catalyst was successfully formed. In addition, no characteristic diffraction peak of ZnO (PDF#36-1451) was observed in the image.…”
In the reaction of carbon dioxide hydrogenation to methanol, CO2 was adsorbed and activated on the oxygen vacancies neighboring Zr species, while the rate-limiting step H2 activation occurred in the Zn–O sites.
“…The characteristic diffraction peaks corresponding to tetragonal phase ZrO 2 (t-ZrO 2 ) (PDF#50-1089) and monoclinic phase ZrO 2 (m-ZrO 2 ) (PDF#83-0941) were found for all these six catalysts from the observed patterns. 39 The diffraction peaks at 2theta = 50° and 62° between ZnO and ZrO 2 were assigned to ZnZrO x solid solution, 23 indicating that the ZnZrO x solid solution catalyst was successfully formed. In addition, no characteristic diffraction peak of ZnO (PDF#36-1451) was observed in the image.…”
In the reaction of carbon dioxide hydrogenation to methanol, CO2 was adsorbed and activated on the oxygen vacancies neighboring Zr species, while the rate-limiting step H2 activation occurred in the Zn–O sites.
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