Hierarchical flower-like zinc oxide nanosheets in-situ growth on three-dimensional ferrocene-functionalized graphene framework for sensitive determination of epinephrine and its oxidation derivative
“…The electroactive surface area was calculated by using following Randles Sevcik equation ( eqn (1) ). 86 i p = 2.69 × 10 5 n 3/2 AD 0 1/2 ν 1/2 C p1 where i p represents the anodic or cathodic peak current, n is the number of electrons transferred, A stands for the area of the electroactive surface (cm 2 ), D 0 denotes the diffusion co-efficient of [Fe(CN) 6 ] 3−/4− (7.6 × 10 −6 cm 2 s −1 ), ν symbolize the scan rate (V s −1 ), and C p represents the concentration of the probe solution ( M ). The electroactive surface area of PW 12 /MOF/P@ERGO/GCE is calculated to be 6.032 cm 2 , according to the calibration equation of i p = 2.239 ν 1/2 − 11.695 ( R 2 = 0.974) presented in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…The electroactive surface area was calculated by using following Randles Sevcik equation (eqn (1)). 86 i p ¼ 2.69 Â 10 5 n 3/2 AD 0 1/2 n 1/2 C p1…”
Section: Effect Of the Electrodeposition Timementioning
Fabrication of a modified glassy carbon electrode based on a polyoxotungstate/metal–organic framework/phosphorus-doped reduced graphene oxide nanohybrid.
“…The electroactive surface area was calculated by using following Randles Sevcik equation ( eqn (1) ). 86 i p = 2.69 × 10 5 n 3/2 AD 0 1/2 ν 1/2 C p1 where i p represents the anodic or cathodic peak current, n is the number of electrons transferred, A stands for the area of the electroactive surface (cm 2 ), D 0 denotes the diffusion co-efficient of [Fe(CN) 6 ] 3−/4− (7.6 × 10 −6 cm 2 s −1 ), ν symbolize the scan rate (V s −1 ), and C p represents the concentration of the probe solution ( M ). The electroactive surface area of PW 12 /MOF/P@ERGO/GCE is calculated to be 6.032 cm 2 , according to the calibration equation of i p = 2.239 ν 1/2 − 11.695 ( R 2 = 0.974) presented in Fig.…”
Section: Resultsmentioning
confidence: 99%
“…The electroactive surface area was calculated by using following Randles Sevcik equation (eqn (1)). 86 i p ¼ 2.69 Â 10 5 n 3/2 AD 0 1/2 n 1/2 C p1…”
Section: Effect Of the Electrodeposition Timementioning
Fabrication of a modified glassy carbon electrode based on a polyoxotungstate/metal–organic framework/phosphorus-doped reduced graphene oxide nanohybrid.
“…Compared with CMC-Cu-CD/GCE, the distance between the oxidation and reduction peaks of rGO-PANI/CD-Cu-CMC/GCE is significantly decreased, which is attributed to the great electron transfer abilities of rGO-PANI. Herein, the electroactive areas of rGO-PANI/CD-Cu-CMC/GCE and the other electrodes can be calculated via the Randles–Sevcik equation: 55,56 I p = 2.69 × 10 5 n 3/2 AD 1/2 v 1/2 C where I p corresponds to the anodic peak current, n corresponds to the number of electrons transferred, A represents the area of the working electrode, v is the scan rate, and C corresponds to the concentration of [Fe(CN) 6 ] 4−/3− . D is the diffusion coefficient (7.6 × 10 −6 cm 2 S −1 ).…”
“…The research outcomes revealed that the doping elements change the ZnO structure. For example, doping elements decrease the crystallite size, increase the crystallinity, and modify the ZnO morphology [ 54 , 55 , 56 , 57 ]. The structural and morphological changes increase the surface-to-volume ratio, creating a more active center at the grain boundaries [ 58 ].…”
Monitoring and detecting carbon monoxide (CO) are critical because this gas is toxic and harmful to the ecosystem. In this respect, designing high-performance gas sensors for CO detection is necessary. Zinc oxide-based materials are promising for use as CO sensors, owing to their good sensing response, electrical performance, cost-effectiveness, long-term stability, low power consumption, ease of manufacturing, chemical stability, and non-toxicity. Nevertheless, further progress in gas sensing requires improving the selectivity and sensitivity, and lowering the operating temperature. Recently, different strategies have been implemented to improve the sensitivity and selectivity of ZnO to CO, highlighting the doping of ZnO. Many studies concluded that doped ZnO demonstrates better sensing properties than those of undoped ZnO in detecting CO. Therefore, in this review, we analyze and discuss, in detail, the recent advances in doped ZnO for CO sensing applications. First, experimental studies on ZnO doped with transition metals, boron group elements, and alkaline earth metals as CO sensors are comprehensively reviewed. We then focused on analyzing theoretical and combined experimental–theoretical studies. Finally, we present the conclusions and some perspectives for future investigations in the context of advancements in CO sensing using doped ZnO, which include room-temperature gas sensing.
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