Abstract:Mixed mercury(II) halogenides were known from long time as good NLO (non-linear optic) materials. The NLO properties are due to the halogen disposition in the solid state and to the...
Birefringent materials are of great significance to the development of modern optical technology; however, research on halide birefringent crystals with a wide transparent range remains limited. In this work, mercuric...
Birefringent materials are of great significance to the development of modern optical technology; however, research on halide birefringent crystals with a wide transparent range remains limited. In this work, mercuric...
“…Both sets of calculations were done with the Crystal17 package, 32 and the basis sets were similar to those used for describing related Hg complexes (see the ESI †). 33 Fig. 4 shows the four models constructed to determine the interaction strength between dimers, the corresponding interaction energies (with and without Grimme's correction), and the bond critical points (BCPs) involving Hg centres.…”
Comproportionation between Hg0 and Hg2+ resulted in the formation of [Hg2(Pip)2] supported by Hg⋯Odioxole and Hg⋯π interactions. Structural and computational assessment determined the tendency of Hg(i) to partake in Hg⋯π interactions.
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