Hg Mercury

Fuel-Mercury Combustion Emissions: An Important Heterogeneous Mechanism and an Overall Review of its Implications

“…Theoretically, there is a suggestion that it may be the partially oxidized carbons on the fly ash surface that initially manage to adsorb the atomic mercury onto the oxygen and not the carbon , . Mercury does have a rich organo-mercurial chemistry that does exhibit direct HgC bonding , . Recently, the mercury fulminate molecule finally has been shown to have direct HgC bonding in its Hg(CNO) 2 structure but is rather unstable .…”

Zinc Alkyls, Edward Frankland, and the Beginnings of Main-Group Organometallic Chemistry

“…Enantioselective alkylation of aldehydes by dialkylzinc reagents has been a very active area of research ever since, and it has been reviewed this year . (See also the organozinc chapters in the first and second , editions of Comprehensive Organometallic Chemistry , as well as other book chapters and reviews. − ) A recent book is devoted wholly to the applications of organozinc reagents in organic synthesis …”

Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ3N,C1,N′}(bromido/chlorido)mercury(II)

“…Organomercury compounds of type R 2 Hg and RHgX (R = alkyl or aryl; X = halide) have received considerable attention in the last three decades, mainly related to the search for versatile reagents in controlled transmetallation reactions (Wardell, 1985). Organomercury(II) derivatives have been used successfully to obtain the desired organometallic compounds of transition metals, as well as main group metals otherwise inaccessible by classical Grignard and/or lithiation reactions (Bonnardel et al, 1996;Gul & Nelson, 1999a,b;Berger et al, 2001Berger et al, , 2003Zhang et al, 2005;Djukic et al, 2006).…”