2015
DOI: 10.1021/acs.nanolett.5b01939
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Hexagonal Silicon Realized

Abstract: Silicon, arguably the most important technological semiconductor, is predicted to exhibit a range of new and interesting properties when grown in the hexagonal crystal structure. To obtain pure hexagonal silicon is a great challenge because it naturally crystallizes in the cubic structure. Here, we demonstrate the fabrication of pure and stable hexagonal silicon evidenced by structural characterization. In our approach, we transfer the hexagonal crystal structure from a template hexagonal gallium phosphide nan… Show more

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Cited by 155 publications
(176 citation statements)
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References 27 publications
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“…The lattice constants a=4.06 Å and c=6.6 Å, extracted from Figure 6(b), agree very well with those reported by Fontcuberta i Morral et al [27] in Si NWs grown using standard chemical vapor deposition at growth temperatures above 500 °C. Those values, however, are different from those reported for 2H Si NW shells where the hexagonal structure was epitaxially imposed by the GaP core [28,29]. Studies carried out elsewhere [30][31][32] show that "anomalous" diffraction patterns could arise from defects of the cubic structure, giving rise to apparent hexagonal patterns due to superposition of different …”
Section: Study Of the Si Nws Structurementioning
confidence: 73%
“…The lattice constants a=4.06 Å and c=6.6 Å, extracted from Figure 6(b), agree very well with those reported by Fontcuberta i Morral et al [27] in Si NWs grown using standard chemical vapor deposition at growth temperatures above 500 °C. Those values, however, are different from those reported for 2H Si NW shells where the hexagonal structure was epitaxially imposed by the GaP core [28,29]. Studies carried out elsewhere [30][31][32] show that "anomalous" diffraction patterns could arise from defects of the cubic structure, giving rise to apparent hexagonal patterns due to superposition of different …”
Section: Study Of the Si Nws Structurementioning
confidence: 73%
“…3 Here, we employ crystal structure transfer, in which we use wurtzite GaP as a template to epitaxially grow SiGe compounds with the hexagonal crystal structure (see figure 1). 4 We show that with this method we can grow defect free hexagonal SiGe shells and branches with tunable Ge concentration. The structural and optical properties of these new crystal phases will be discussed.…”
mentioning
confidence: 86%
“…While such lamellae should not be considered a 2H hexagonal phase, there is sufficient evidence that well‐ordered … ( A b )( B a )… stacking of tetrahedral planes (Figs and ) occurs at scales up to, at least, tens of nanometers for C (e.g. see Chen et al , ; Daulton et al , ; Lifshitz et al , ; Kulnitskiy et al , ; Kraus et al , ), Si (Dahmen et al , ; Cerva, ; Algra et al , ; Hauge et al , ), Ge (Xiao and Pirouz, ; Vincent et al , ) and SiC (Daulton et al , ). Therefore, lonsdaleite, as well as other 2H hexagonal‐diamond isostructural phases, do exist on at least this spatial scale.…”
Section: The Nanodiamond Evidencementioning
confidence: 99%