Heterothiometallic polymeric clusters

Crystal structure of tris(tetramethylammonium) tetrakis(μ2-sulfido)-tetrasulfidocopper(I)-dimolybdenum(VI), [N(CH3)4]3[CuMo2S8]

“…Heterothiometallic Mo/W-S-Cu/Ag clusters are well known for their structural richness [1], relevance to some biological processes [2] and promising applications as third-order non-linear optical (NLO) materials [3]. (2) [ 6].…”

Synthesis, structure and properties of three 1D d10 metal–organic coordination polymers with 5-amino-2,4,6-triiodoisophthalic acid

“…[1][2][3][4][5][6][7][8][9][10][11]. The construction of CPs depends on the combination of several factors, such as the coordination geometry of metal nodes, the nature of organic ligands, the use of noncovalent interactions, the ratio between metal ion and ligand, and sometimes the reaction temperature [12][13][14][15][16][17][18][19].…”

Preparation and characterization of two supramolecular complexes with 5-amino-2,4,6-triiodoisophthalic acid under N-donor auxiliary ligand intervention

“…The aim of contemporary supramolecular chemistry and crystal engineering is the development of new crystalline materials with various functions and possible applications such as molecular adsorption, magnetism, nonlinear optics, molecular sensing, heterogeneous catalysis, and photoactive materials although the rational design and synthesis of metal-organic frameworks (MOFs) with target structure and function still remains a long-term challenge [1][2][3][4][5][6][7][8][9][10][11]. The construction of supramolecular architectures depends on the combination of several factors, such as the coordination geometry of metal ions, the nature of organic ligands, the use of noncovalent interactions (hydrogen bonding, halogen bonding, p-p interactions, or their combination in different ways) and sometimes the reagent ratio [12][13][14][15].…”