Heterogeneous ethylene hydroformylation on polymer supported Rh-based catalysts: a DFT analysis of the mechanism and Rh–P effect

Ma, Jing; Liu, Meizhe; Zhu, Mingxuan; Wang, Yutong; Zhou, Yamei; Wang, Baohe

doi:10.1039/d2cy00924b

Catal. Sci. Technol.

2022

DOI: 10.1039/d2cy00924b

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Heterogeneous ethylene hydroformylation on polymer supported Rh-based catalysts: a DFT analysis of the mechanism and Rh–P effect

Jing Ma

Meizhe Liu

Mingxuan Zhu

et al.

Abstract: The loss of precious metal Rh exists in the homogeneous catalytic formation of propionaldehyde by ethylene hydroformylation. Recently, Rh-based catalysts supported on porous vinyl triphenylphosphine (3V-PPh3) polymers have been recommended...

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Carbonylation Reactions Using Single‐Atom Catalysts

Jurado,

Posada‐Pérez,

Axet

2024

ChemCatChem

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The development of highly efficient and selective catalysts for carbonylation reactions represents a significant challenge in catalysis. Single‐atom catalysts (SACs) have postulated as promising candidates able to combine the strengths of both homogeneous and heterogeneous catalysts. In this paper, we review recent advances in tailoring solid supports for SACs to enhance their catalytic performance in carbonylation reactions. We first discuss the effect of supports on the hydroformylation reaction catalysed by SACs, followed by recent advances for methanol, ethanol, and dimethyl ether carbonylation reactions, focusing on the design of halide‐free catalysts with improved activity and stability. Overall, this review highlights the importance of tailoring solid supports for SACs to achieve highly active and selective catalysts in carbonylation reactions, paving the way for future developments in sustainable catalysis.

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Carbonylation Reactions Using Single‐Atom Catalysts

Jurado,

Posada‐Pérez,

Axet

2024

ChemCatChem

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Stable and robust single transition metal atom catalyst for CO2 reduction supported on defective WS2

Ismail

Ali

Raziq

et al. 2023

Applied Surface Science

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Heterogeneous ethylene hydroformylation on polymer supported Rh-based catalysts: a DFT analysis of the mechanism and Rh–P effect

Abstract: The loss of precious metal Rh exists in the homogeneous catalytic formation of propionaldehyde by ethylene hydroformylation. Recently, Rh-based catalysts supported on porous vinyl triphenylphosphine (3V-PPh3) polymers have been recommended...

Cited by 2 publications

References 32 publications

Carbonylation Reactions Using Single‐Atom Catalysts

Carbonylation Reactions Using Single‐Atom Catalysts

Stable and robust single transition metal atom catalyst for CO2 reduction supported on defective WS2

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