Heterodinuclear Diphosphane-Bridged Iron–Platinum Diyne Complexes as Metalloligands for the Assembly of Polymetallic Systems (Fe, Pt, Co)

Crystal structure of dicarbonyl[μ2-methylenebis(diphenylphosphane)-κ2P:P′][μ2-2-(2,4,5-trimethylphenyl)-3-oxoprop-1-ene-1,3-diyl](triphenylphosphane-κP)ironplatinum(Fe—Pt)–dichloromethane–toluene (1/1/2), [(OC)2Fe(μ-dppm)(μ-C(=O)C(2,4,5-C6H2Me3)=CH)Pt(PPh3)]

“…group and the Fe1-Pt1 bond length of 2.5770 (5) Å is in the range, 2.5453 (9) to 2.597 (4) Å , encountered for similar dppm-bridged compounds, e.g. (Mohamed et al, 2019;Fontaine et al, 1988). When the metals are not spanned by a diphosphane ligand, the Fe-Pt bond distance is slightly longer, as in [(OC)…”

1-(4-Formyl-2,6-dimethoxyphenoxy)-4-chlorobut-2-yne

“…Selected examples [13][14][15][16] of coordination compounds obtained from alkyne-containing molecules.…”

Synthesis of Tris(arylphosphite)-ligated Cobalt(0) Complexes [Co2(CO)6{P(OAr)3}2], and their Reactivity towards Phenylacetylene and Diphenylacetylene

“…However, there are no reports on the structural features of aryl phosphite-substituted dimetallatetrahedranes [{(ArO)3P}(OC)2Co-Co(μ-RCCR)(CO)2{P(OAr)3}]. In this study on the reactivity of metal-metal bonded dinuclear complexes with alkynes [30][31][32][33][34][35][36], an unknown complex, namely [Co2(CO)6{P(OTol-o)3}2] 1b, was synthesized along with [Co2(CO)6{P(OPh)3}2] 1a and reacted with phenylacetylene and diphenylacetylene. The resultant Co(0) complexes were characterized in solution by IR and multinuclear NMR spectroscopy as well as four single-crystal X-ray diffraction studies.…”