1995
DOI: 10.1039/jm9950502167
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Helical twisting power of chiral mono- and bis-aminoanthraquinones. Intramolecular and intermolecular chirality transfer in liquid-crystal phases

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Cited by 39 publications
(39 citation statements)
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“…Values of TD mic S° are large compared with those for ionic surfactants, for which the disrupting influence of ionic head groups on the ordering of water around the monomer is greater. TD mic S° per CH 2 averages roughly 0.7 kJ mol 21 . The main driving force of micellization at 40 °C is the entropy term supported in some cases by an exothermic enthalpy term.…”
Section: Scheme 17mentioning
confidence: 96%
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“…Values of TD mic S° are large compared with those for ionic surfactants, for which the disrupting influence of ionic head groups on the ordering of water around the monomer is greater. TD mic S° per CH 2 averages roughly 0.7 kJ mol 21 . The main driving force of micellization at 40 °C is the entropy term supported in some cases by an exothermic enthalpy term.…”
Section: Scheme 17mentioning
confidence: 96%
“…The contribution of each methylene group on going from C 8 to C 12 to the enthalpy of micellization, D mic H° (CH 2 ), is approximately 22.4 kJ mol 21 . This pattern is in good agreement with increments reported for other surfactants.…”
Section: Scheme 17mentioning
confidence: 99%
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“…The pitch or the HTP are also chirality measurements which give like the ACD "anisotropic chirality information". 16,19 Both chirality measurements, pitch and HTP, on one hand, and CD on the other hand, can be traced back to the absolute configuration of the chiral molecule. Therefore, the question arises whether there is a correlation between both different chirality measurements when as a presupposition the same regions of the molecule are responsible for both effects.…”
Section: Chiral Phases With and Without Suprastructural Chiralitymentioning
confidence: 99%