Heavy-Atom Tunneling in Ring-Closure Reactions of Beryllium Ozonide Complexes
Yangyu Zhou,
Wenbin Fan,
Jingjing Tang
et al.
Abstract:Quantum mechanical tunneling (QMT) has long been recognized as crucial for understanding chemical reaction mechanisms, particularly in reactions involving light atoms like hydrogen. However, recent findings have expanded this understanding to include heavy-atom tunneling reactions. In this report, we present the observation of two heavy-atom tunneling reactions involving the spontaneous conversions from end-on bonded beryllium ozonide complexes, OBeOOO (A) and BeOBeOOO (C), to their corresponding side-on bonde… Show more
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