Heat-Resistant Polymer-Grafted Carbon Black: Grafting of Poly(Organophosphazenes) onto Carbon Black Surface

Tsubokawa, Norio; Tsuchida, Hideyo

doi:10.1080/10101329208052163

Cited by 14 publications

(2 citation statements)

References 23 publications

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“…On the contrary, surface modification of conventional organic polymeric materials using poly(organophosphazenes) has been achieved basically by two different synthetic approaches, i.e., surface coating , and surface grafting reactions of different phosphazene macromolecules on poly(ethylene), poly(propylene), poly(vinyl chloride), poly(ethylene terephthalate), poly(bisphenol A carbonate), poly(methylmethacrylates), poly(vinyl alcohol), − poly(ethylene-co-vinyl alcohol), and on carbon black …”

Section: Introductionmentioning

confidence: 99%

Surface Functionalization with Phosphazenes, Part 3: Surface Modification of Plasma-Treated Polyethylene with Fluorinated Alcohols Using Chlorinated Phosphazenes as Coupling Agents

et al. 2007

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In this paper, we present a new strategy to functionalize the surface of high-density polyethylene plates using a cold plasma technique and chlorinated phosphazenes as coupling agents. The clean surface of polyethylene samples was modified by argon plasma treatments to introduce polar groups (e.g., CdO, COOR, OR, OH, etc.); the free hydroxylic functions thus introduced were successively reacted with (NPCl 2 ) 3 and (NPCl 2 ) n to graft these substrates onto the surface of the polymer samples through the formation of strong covalent Cl-P-O-HDPE bonds. The residual unreacted chlorines, still present in the phosphazenes, were eventually substituted with alkoxy substituents (e.g., trifluoroethanol and heptadecafluorononanol) according to the classical nucleophilic substitution reaction of both cyclic and polymeric phosphazene materials. In this way, surface features of polyethylene samples could be deeply modified in a rather general and easy way.

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Section: Introductionmentioning

confidence: 99%

Surface Functionalization with Phosphazenes, Part 3: Surface Modification of Plasma-Treated Polyethylene with Fluorinated Alcohols Using Chlorinated Phosphazenes as Coupling Agents

et al. 2007

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“…In addition grafting of polymers onto these surfaces interests us for designing new functional composite materials which have the excellent properties both of nanoparticles as mentioned above and of grafted polymers, such as photosensitivity, biorepellent activity, antibacterial activity, and pharmacological activity (Tsubokawa, 2007). We have succeeded in the grafting of various polymers such as vinyl polymer (Tsubokawa et al, 1988a;Tsubokawa et al, 1990;Fujiki et al, 1990;Tsubokawa et al, 1992a), polyester (Tsubokawa et al, 1982;Tsubokawa et al, 1983), polyether (Tsubokawa et al, 1986;Tsubokawa et al, 1988b), poly(organophosphazene) (Tsubokawa et al, 1992b), and poly(dimethysiloxane) (Tsubokawa et al, 1992c) onto silica nanoparticle and carbon black surfaces using surface functional groups as grafting sites. Furthermore, many experimental attempts by other researchers also have been made to graft polymers onto silica nanoparticle and carbon black surfaces.…”

Section: Introductionmentioning

confidence: 99%