2017
DOI: 10.1002/jsid.542
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Heat- and water-proof quantum dot/siloxane composite film: Effect of quantum dot-siloxane linkage

Abstract: We report on the effect of linkage between quantum dot (QD) and siloxane matrix by preparing two different QD/siloxane films. One has chemical linkages between QD and siloxane matrix, and the other has no chemical linkages between QD and siloxane matrix. The QD/siloxane (methacryl) film, which has the chemical linkages, exhibits no degradation of photoluminescence (PL) quantum yield (QY) under heat or moisture condition for over 1 month, while the QD/siloxane (epoxy) film, which has no linkages, shows drastic … Show more

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Cited by 6 publications
(2 citation statements)
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“…The hydrogen functional group can react with vinyl group in siloxane matrix and oleic acid. [11] It can enhance thermal stability of QD due to its high thermal stability. In addition, siloxane hybrid LED encapsulant much improve the stabilities of QDs compared with previous reported photo SE-QD, which have methacryl functional group with low degradation temperature.…”
Section: Introductionmentioning
confidence: 99%
“…The hydrogen functional group can react with vinyl group in siloxane matrix and oleic acid. [11] It can enhance thermal stability of QD due to its high thermal stability. In addition, siloxane hybrid LED encapsulant much improve the stabilities of QDs compared with previous reported photo SE-QD, which have methacryl functional group with low degradation temperature.…”
Section: Introductionmentioning
confidence: 99%
“…Polymer-based luminescent films are frequently used in sensors, , solar concentrators, , and light-emitting diodes (LEDs). , Fabrication of such composite films often involves two processes: (i) synthesis of the luminescent component, such as an organic dye, semiconductor quantum dots (QDs), or metal nanoclusters (NCs) in solution, and (ii) dispersion of these in a monomer or a dissolved polymer, followed by polymerization/evaporation of the solvent. However, widespread application of this approach is in part hindered by several limitations: (i) sometimes poor dispersion of luminescent components in the polymer, leading to the phase segregation which makes it difficult to fabricate large-area, uniformly luminescent films; (ii) deterioration of the photoluminescence (PL) quantum yield (QY) of the luminescent component during the fabrication process of the film; (iii) poor PL stability, particularly when the films are exposed to heat, oxygen, or moisture. …”
Section: Introductionmentioning
confidence: 99%