Site
Ordovician limestone karst water plays a key role in the release
of heavy metals from abandoned coal gangue or filled-in goafs in closed
coal mines. In this study, a series of immersion experiments was performed
to evaluate the leaching behavior of heavy metals in coal gangue from
the Baizhuang coal mine in Shandong Province. The experiment was conducted
with different immersion solutions, including site Ordovician limestone
karst water (pH 7.3) that was compared to three solution pH levels
(pH 5.3, 7.3, and 9.3), over a maximum duration of 648 h. The surface
structure, chemical composition of the original coal gangue and post-leached
residue, and multiple water quality parameters [pH, oxidation reduction
potential (ORP), electrical conductivity (EC), total dissolved solids
(TDS), and dissolved oxygen (DO)] of the immersion solutions were
analyzed using scanning electron microscopy–energy-dispersive
spectroscopy (SEM–EDS), X-ray fluorescence spectrometry (XRF),
and a Hach Hydrolab multiparameter water quality analyzer, respectively.
The results indicated that the site karst water presented quite different
implications for heavy metal dissolution compared to laboratory solutions
having the same and different pH levels as the karst water, which
often showed the lowest values of heavy metal concentrations for the
four solutions. Although the heavy metal releases did not change in
order of increasing solution pH levels, the dissolved quantities of
heavy metals in the four solutions showed a generally similar development
trend with processing using increasing immersion times and increased
almost to the maximum time used, except that Pb exhibited a strong
increase followed by a decline. Additionally, the pH, ORP, EC, TDS,
and DO values for the coal gangue at different solutions over time
showed marked differences. Additionally, the SEM–EDS and XRF
results showed that stable heavy metals, including Mn and Pb, released
more readily in site karst water or neutral solutions than in acidic
and alkaline solutions but unstable heavy metals, including Fe, Zn,
and Cu, more easily released under acidic and alkaline solutions.
In abandoned coal mines, coal gangues under the effects of site Ordovician
limestone karst waters may pose a lesser environmental problem than
indicated by the laboratory results.