2021
DOI: 10.1007/978-3-662-55939-0
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Handbuch der chemischen Elemente

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“…To deposit double the thickness, the evaporation chamber had to be opened to reload with BaS powder. During this time, the BaS film is exposed to air and reacts with water to form Ba(OH) 2 and H 2 S gas at the surface, [ 33 ] which then is enclosed by the second BaS layer and possibly released as gas again during the sulfurization process. The cracks in the films are most likely created during the rapid cooling of the sample due to the difference in expansion coefficients between substrate and film.…”
Section: Resultsmentioning
confidence: 99%
“…To deposit double the thickness, the evaporation chamber had to be opened to reload with BaS powder. During this time, the BaS film is exposed to air and reacts with water to form Ba(OH) 2 and H 2 S gas at the surface, [ 33 ] which then is enclosed by the second BaS layer and possibly released as gas again during the sulfurization process. The cracks in the films are most likely created during the rapid cooling of the sample due to the difference in expansion coefficients between substrate and film.…”
Section: Resultsmentioning
confidence: 99%