Halogen bonding–driven chiral amplification of a bimetallic gold-copper cluster through hierarchical assembly
Ya-Jie Wang,
Xiao-Yan Shi,
Pengyao Xing
et al.
Abstract:Understanding the fundamentals and applications of chirality relies substantially on the amplification of chirality through hierarchical assemblies involving various weak interactions. However, a notable challenge remains for metal clusters chiral assembly driven by halogen bonding, despite their promising applications in lighting, catalysis, and biomedicine. Here, we used halogen bonding–driven assembly to achieve a hierarchical degree of achiral emissive
Au
2
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