Abstract:Reaction of alkoxyhalogenation 3-organyloxy-1-propenes with N-bromosuccinimide (or iodine) in dimethylacetylenecarbinol medium proceeds regioselectively according to NMR spectra. It proceeds at a low temperatureç cooling the reaction mixture with ordinary ice. The main reaction products, diethers -3-bromo (iodine) -1,2-propanediol, are formed in high yields. İt founded that the alkoxyhalogenation of allyl ethers with propinol proceeds regioselectively with fixation of the halogen atom to the peripheral carbon … Show more
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