Abstract:Compounds [BuN][VO(oda)⊂2Cl], 1, [BuN][VO(glut)⊂2Cl], 2, and [BuN][VO(glut)⊂F], 3, (oda = oxydiacetate, O(CHCOO); glut = glutarate, CH(CHCOO)) were obtained by a stepwise reaction of in situ prepared [BuN]VO with HCl (or HF for 3) and then with the dicarboxylic acid X(CHCOOH) (X = O and CH), under appropriate reaction conditions. Multinuclear magnetic resonance (H, C{H}, Cl,F and V), electrochemical studies, X-ray structural determinations (single crystal and powder), thermogravimetric analyses (TGA) and Densi… Show more
A self-assembled metallobox from copper(II) and two macrocycles containing 1H-pyrazole ligands has been prepared. The internal cavity of the box is able to selectively encapsulate a single chloride anion over...
A self-assembled metallobox from copper(II) and two macrocycles containing 1H-pyrazole ligands has been prepared. The internal cavity of the box is able to selectively encapsulate a single chloride anion over...
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