Half-sandwich iron complexes bearing vinyl-selenocarboxylato ligands

Al-Jazzazi, Taghreed; El‐khateeb, Mohammad; Quraan, Lama; Abul‐Futouh, Hassan; Görls, Helmar; Weigand, Wolfgang

doi:10.1007/s12039-019-1732-4

J Chem Sci

2020

DOI: 10.1007/s12039-019-1732-4

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Half-sandwich iron complexes bearing vinyl-selenocarboxylato ligands

Taghreed Al-Jazzazi

Mohammad El‐khateeb

Lama Quraan

et al.

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Cited by 5 publications

References 23 publications

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Half‐Sandwich Iron Chalcogenopropargylcarbonato Complexes as CO‐Releasing Molecules

Al‐Shboul,

El‐khateeb,

Jazzazi

et al. 2024

Applied Organom Chemis

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Interaction of iron chalcogenides (μ‐Ex)[CpFe(CO)2]2 (E = S; x = 2–4, E = Se, x = 1) with propargyl chloroformate (ClCO2CH2C≡CH) in diethyl ether yielded iron(II) chalcogenopropargylcarbonato complexes CpFe(CO)2ECO2CH2C≡CH (E = S (1), Se (2)). These complexes have been characterized by elemental analysis, UV–Vis, IR, and 1H‐ and 13C{1H}‐NMR spectroscopy and single‐crystal x‐ray diffraction techniques. Further, the suitability of complexes 1 and 2 as CO‐releasing molecules (CORMs) for the administration of carbon monoxide has been studied. CO gas is released upon irradiation of THF solution of these complexes in the presence of hemoglobin.

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Half‐Sandwich Iron Chalcogenopropargylcarbonato Complexes as CO‐Releasing Molecules

Al‐Shboul,

El‐khateeb,

Jazzazi

et al. 2024

Applied Organom Chemis

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Cyclopentadienyl iron dicarbonyl styrene chalcogenosulfonates: synthesis and structure of CpFe(CO)2SeSO2CH=CHPh

et al. 2022

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In this contribution, we report the preparation of iron thiosulfonato complex CpFe(CO) 2 SSO 2 CH=CHPh (1) and its selenosulfonato analogue CpFe(CO) 2 SeSO 2 CH=CHPh (2) featuring styrene moiety. 1 and 2 are obtained by electrophilic attack of (l-E x )[CpFe(CO) 2 ] 2 (E = S; x = 2-4, E = Se; x = 1) on the sulfur atom of styrene sulfonyl chloride ClSO 2 CH=CHPh. The new compounds, 1 and 2 have been characterized by elemental analyses, IR, 1 H-, 13 C{ 1 H}-NMR, UV-Vis spectroscopy and the structure of 2 is determined by X-ray crystallography.

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Synthesis and characterization of mono- and bi-iron chalcogeno-ferrocenylcarboxylato complexes

El-khateeb,

Al-Momani,

Garcia-Orduna

et al. 2024

Journal of Molecular Structure

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Half-sandwich iron complexes bearing vinyl-selenocarboxylato ligands

Cited by 5 publications

References 23 publications

Half‐Sandwich Iron Chalcogenopropargylcarbonato Complexes as CO‐Releasing Molecules

Half‐Sandwich Iron Chalcogenopropargylcarbonato Complexes as CO‐Releasing Molecules

Cyclopentadienyl iron dicarbonyl styrene chalcogenosulfonates: synthesis and structure of CpFe(CO)2SeSO2CH=CHPh

Synthesis and characterization of mono- and bi-iron chalcogeno-ferrocenylcarboxylato complexes

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