We report the observation of spin domain walls bounded by half-quantum vortices (HQVs) in a spin-1 Bose-Einstein condensate with antiferromagnetic interactions. A spinor condensate is initially prepared in the easy-plane polar phase, and then, suddenly quenched into the easy-axis polar phase. Domain walls are created via the spontaneous Z2 symmetry breaking in the phase transition and the walls dynamically split into composite defects due to snake instability. The end points of the defects are identified as HQVs for the polar order parameter and the mass supercurrent in their proximity is demonstrated using Bragg scattering. In a strong quench regime, we observe that singly charged quantum vortices are formed with the relaxation of free wall-vortex composite defects. Our results demonstrate a nucleation mechanism for composite defects via phase transition dynamics.Topological defects in a continuous ordered system are a splendid manifestation of symmetry breaking, with their fundamental types, such as walls, strings, and monopoles, inevitably determined by the topology of the order parameter space. However, if there is a hierarchy of energy (length) scales with different symmetries, composite defects, such as domain walls bounded by strings and strings terminated by monopoles may exist in the system [1]. In cosmology, it has been noted that such composite defects can be nucleated through successive phase transitions with different symmetry breaking in grand unification theories; furthermore, composite defect formation has been proposed as a possible mechanism for galaxy formation [1,2] and baryogenesis [3] in the early Universe.Spinful superfluid systems with multiple symmetry breaking provide an experimental platform for studying the physics of composite defects and, thus, to examine the cosmological scenario. In superfluid 3 He-B, it has been observed that a spin-mass vortex, on which a planar soliton terminates, can survive after phase transitions by being pinned on the vortex lattice [4,5] or nafen [6]. Composite defects have also been theoretically studied in the atomic Bose-Einstein condensate (BEC) system. Vortex confinement with a domain wall was predicted to occur in a two-component BEC under coherent intercomponent coupling [7]. In particular, for a spin-1 Bose gas with antiferromagnetic interactions, half-quantum vortices (HQVs) joined by a spin domain wall were anticipated to be responsible for the emergence of an exotic 2D superfluid phase with spin-singlet pair correlations [8,9].In this Letter, we report the experimental observation of wall-vortex composite defects in a quasi-2D antiferromagnetic spin-1 BEC. The composite defects are nucleated via a two-step instability mechanism in quantum quench dynamics from the easy-plane polar (EPP) phase into the easy-axis polar (EAP) phase. In the first step, * yishin@snu.ac.kr spontaneous Z 2 symmetry breaking causes domain wall formation, the core of which is occupied by the EPP phase. In the second step, the snake instability splits the domain walls into ...