Let G be a reductive group defined over an algebraically closed field of characteristic 0 such that the Dynkin diagram of G is the disjoint union of diagrams of types G 2 , F 4 , E 6 , E 7 , E 8 . We show that the degree 3 unramified cohomology of the classifying space of G is trivial. In particular, combined with articles by Merkurjev [10] and the author [1], this completes the computations of degree 3 unramified cohomology and reductive invariants for all split semisimple groups of a homogeneous Dynkin type.