2006
DOI: 10.1143/jjap.45.l720
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Growth of Super Long Aligned Brush-Like Carbon Nanotubes

Abstract: Efficient chemical vapor deposition (CVD) synthesis of super long (7 mm) aligned carbon nanotubes (CNTs) with highdensity is reported here. Activity of catalyst nanoparticles has been achieved for very long time periods (ca. 12 h) by optimization of experimental parameters. The relative levels of ethylene and water, as well as those of ethylene and H 2 , were found to be most important for achieving extended-time activity of the catalyst. Transmission electron microscope (TEM) images revealed that the nanotube… Show more

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Cited by 91 publications
(81 citation statements)
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“…The results are summarized in Table 1. The CNT synthesis ratio q in this work is almost 712 times of that in [4] and 1.4 times of that in [14]. In this work, the synthesis time was 60 min, ethylene flow rate was 40 sccm and the iron film thickness is 2 nm.…”
Section: Resultsmentioning
confidence: 79%
See 1 more Smart Citation
“…The results are summarized in Table 1. The CNT synthesis ratio q in this work is almost 712 times of that in [4] and 1.4 times of that in [14]. In this work, the synthesis time was 60 min, ethylene flow rate was 40 sccm and the iron film thickness is 2 nm.…”
Section: Resultsmentioning
confidence: 79%
“…There have been many reports dealing with the synthesis of well-aligned MW-CNTs [5][6][7][8][9][10] and single-walled carbon nanotubes (SW-CNTs) [11,12]. Liquid precursor [7,13] and water assisted methods [11,12,14] were introduced to synthesize ultralong CNT forest. All of these studies used either water assisted or carbon source added in water to increase the catalyst activity and to elongate CNT length.…”
Section: Introductionmentioning
confidence: 99%
“…The resulting low catalytic activity of CNT synthesis has not only reduced the availability of SWNTs, but the dead catalysts remain in the as-grown material as impurities. Addition of a controlled amount of water vapor in the growth ambient can dramatically enhance the activity and lifetime of the catalysts and address these problems [157][158][159][160][161]. This new CVD approach denoted as "supergrowth", works best on substrates with catalytic nanoparticles.…”
Section: Supergrowthmentioning
confidence: 99%
“…For nanotubes with larger length [8] one of the most important scattering mechanisms should originate from acoustic phonons. In the reference [9] for the different mechanisms of electron scattering by acoustic phonons analytical formulas for the conductivity of a quantum cylinder in a longitudinal magnetic field were obtained, taking into account effects of phonon confinement.…”
Section: Introductionmentioning
confidence: 99%