Single -crystal growth of Tm 3þ -doped Y 2 O 3 , Sc 2 O 3 , and Lu 2 O 3 sesquioxides, with a melting point around 2400 °C, by the micropulling down technique is reported. Crystal quality and composition of the crystals were evaluated by rocking curve and energy-dispersive X-ray (EDX) analyses, respectively. Optical properties including optical transmittance and photoluminescence decay profiles were also examined. Furthermore, scintillation performance of the crystals including pulse height spectra and radioluminescence spectra under R-ray and γ-ray excitation was evaluated.