2013
DOI: 10.1007/bf03353739
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Growth and Formation Mechanism of Branched Carbon Nanotubes by Pyrolysis of Iron(II) Phthalocyanine

Abstract: Abstract:In this letter, a route for synthesizing vertically aligned multi-walled carbon nanotubes (MWCNTs) with branched nanotubes in large area was reported. The branched MWCNTs up to about 30% can be generated by the pyrolysis of iron(II) phthalocyanine in presence of thiol under Ar/H2 at 800∼900℃. The growth mechanism of the branched nanotubes was proposed and the possible reason that thiol enhanced branched nanotubes growth is discussed. The as-prepared samples provide a suitable candidate to investigate … Show more

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Cited by 9 publications
(6 citation statements)
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References 27 publications
(13 reference statements)
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“…This is considerably lower as the adhesion of real gecko footpads (10 N/cm 2 ) [ 19 ], but the adhesion strength might be improved by smaller CNF diameters leading to a higher density and improvement of the CNF orientation resulting in more CNFs in contact with the surface. Additionally, hierarchically structured CNFs, such as Y-shaped CNFs [ 45 46 ], might help to better mimic a real gecko footpad, leading to an improved adhesion strength of artificial structures based on CNFs. Overall, the measurements demonstrate that CNF arrays have the potential for applications relying on adhesives with long-term stability under harsh environments.…”
Section: Resultsmentioning
confidence: 99%
“…This is considerably lower as the adhesion of real gecko footpads (10 N/cm 2 ) [ 19 ], but the adhesion strength might be improved by smaller CNF diameters leading to a higher density and improvement of the CNF orientation resulting in more CNFs in contact with the surface. Additionally, hierarchically structured CNFs, such as Y-shaped CNFs [ 45 46 ], might help to better mimic a real gecko footpad, leading to an improved adhesion strength of artificial structures based on CNFs. Overall, the measurements demonstrate that CNF arrays have the potential for applications relying on adhesives with long-term stability under harsh environments.…”
Section: Resultsmentioning
confidence: 99%
“…This will result in the enlargement of iron particles which is responsible for nanotube growth." This finding is important, as they noted that these larger particles were more likely to split into smaller ones, leading to branched nanotube growth [13].…”
Section: Experimental Studies and Branched Cns Productionmentioning
confidence: 96%
“…To create branched junctions of CNTs, one can use various methods and approaches, including direct growth [11,12,13], high-energy electron beam irradiation [14,15,16], forming junctions in strong electrical, optical, and thermal fields [17,18,19], as well as using atomic force microscopy [20]. The laser nanowelding technique seems to be the most promising method for obtaining high-quality 3D scaffolds from CNT junctions [21].…”
Section: Introductionmentioning
confidence: 99%