Cd 1-x Zn x S-sensitized K 4 Nb 6 O 17 composite photocatalysts (designated Cd 1-x Zn x S/K 4 Nb 6 O 17 ) were prepared via a simple deposition-precipitation method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectrometry (EDS), N 2 sorption, ultraviolet-visible light diffuse reflectance spectroscopy (UV-Vis DRS), photoluminescence measurements (PL), and X-ray photoelectron spectroscopy (XPS). The Cd 0.8 Zn 0.2 S particles were scattered on the surface of K 4 Nb 6 O 17 , and had a relatively uniform size distribution around 50 nm. The absorption edge of K 4 Nb 6 O 17 was shifted to the visible light region and the recombination of photo-generated electrons and holes suppressed after Cd 0.8 Zn 0.2 S loading. The Cd 0.8 Zn 0.2 S(25 wt %)/K 4 Nb 6 O 17 composite possessed the highest photocatalytic activity for hydrogen production under visible light irradiation, evolving 8.278 mmol/g in 3 h. Recyclability tests were performed, and the composite photocatalysts were found to be fairly stable. The mechanism of charge separation between the photogenerated electrons and holes at the Cd 0.8 Zn 0.2 S/K 4 Nb 6 O 17 composite was discussed.