“…Reduced Non-local pseudo-potential method also suggests that there is not likely to be any indirect energy gap less than direct band gap for CdTe or ZnTe. It is suggested that at lower photon energy transitions, presence of high density defects, charge impurities and disorders at grain boundaries could cause a decrease in direct band-gap [22][23][24]. So presence of non-reacted Zn and/or Cd contributed to reduction of band-gap.…”