Group IV organometallic sulfur compounds

Davidson, Wenzel E.; Hills, K.; Henry, Malcolm C.

doi:10.1016/s0022-328x(00)84648-3

Cited by 40 publications

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“…10,11 Of particular interest is that this regioselectivity is apparently unique to silicon among the Group 14 elements, as compounds containing electrophilic carbon, germanium, tin, and lead react with mercaptoalcohols only through the thiol group. [12][13][14][15] The reaction conditions for these syntheses are mild, and simply involve overnight stirring of the chlorosilane, mercaptoalcohol, and triethylamine in diethyl ether at room temperature. After removal of the hydrochloride salt by filtration, the volatiles are removed under reduced pressure and the crude product is distilled.…”

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Multifunctional thiols from the highly selective reaction of mercaptoalcohols with chlorosilanes

Jennings

Son

2013

Chem. Commun.

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confidence: 99%

Multifunctional thiols from the highly selective reaction of mercaptoalcohols with chlorosilanes

Jennings

Son

2013

Chem. Commun.

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“…The organotin derivatives n-Bu3Sn(SC6F5) and n-Bu2Sn-(SC6F5), have been prepared from the corresponding organotin oxide and pentafluorothiophenol (21). Bis(pentafluoro-pheny1thio)diphenyl lead decomposed at room temperature according to the equation A similar decomposition has been observed for bis(pheny1thio)diphenyl lead (22). Pentafluorothiophenol is readily oxidized, as are most thiols (2), to bis(pentafluor0-pheny1)-disulfide; bromine has been used as an oxidant (4).…”

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Some reactions of pentafluorothiophenol. Preparation of some pentafluoro-phenylthio metal derivatives

Peach¹

1968

Can. J. Chem.

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The new con~pounds M(SC6F5), where M = Cs, TI, Cu, Au, and Ph3Pb; M(SC6F5),, where M = Pb, Cd, Hg, Ni, and Pt; M(SC6F&, where M = As or Bi; and Sn(SC6F5),, have been prepared from pentafluorothiophenol and metal ions in aqueous solution. Zn(SC6F,)2 has been prepared from zinc oxide and pentafluorothiophenol in methanol. The co~npounds have been characterized, and their infrared spectra and 'H and 19F nuclear magnetic resonance spectra examined.Some of the reducing properties of pentafluorothiophenol and its polymerization have been studied.Canadian Journal of Chernislry, 46, 2699Chernislry, 46, (1968 The reactions, if any, of an aqueous suspension of pentafluorothiophenol with various metal ions can be divided into three categories, (1) formation of pentafluoro-phenylthio metal derivatives, (2) reduction forming bis(pentafluor0-phenyl) disulfide, and (3) polymerization forming perfluoropoly(pheny1ene sulfide); one specific reaction or a combination may be observed with a particular metal ion. This paper describes the reactions of pentafluorothiophenol with aqueous solutions containing the ions, or compounds, Cs', Pb2+,

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With Group‐IVB–Group‐VIIB Bonds

Hagen¹

1991

Inorganic Reactions and Methods

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Group IV organometallic sulfur compounds

Cited by 40 publications

References 12 publications

Multifunctional thiols from the highly selective reaction of mercaptoalcohols with chlorosilanes

Multifunctional thiols from the highly selective reaction of mercaptoalcohols with chlorosilanes

Some reactions of pentafluorothiophenol. Preparation of some pentafluoro-phenylthio metal derivatives

With Group‐IVB–Group‐VIIB Bonds

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