Total carbon, nitrogen, and phosphate parameters were studied for the first time in the groundwater in the Silifke coastal plain, which is a RAMSAR site in Turkey. Seasonal variations of these parameters in the plain were examined based on groundwater data collected from 21 wells during the winter, spring, summer, and fall seasons. Total dissolved organic carbon (DOC), inorganic carbon (DIC), inorganic phosphate (DIP), inorganic nitrogen (DIN), and total alkalinity (TAlk) average values in the groundwater were low in all seasons (<2.2 mg/L for DOC; <54 mg/L for DIC; <0.06 mg/L for DIP; <1.5 mg/L for DIN; <232 mg/L for TAlk). The results showed a strong relationship between DIC and HCO À 3 as expected. The results indicate that the content of these parameters in the groundwater of Silifke coastal plain pose no or little risk at present. However, computed Langelier Saturation Index (LSI) values indicated that the groundwater has a tendency to form scale and CaCO 3 precipitation may occur.
IntroductionIn natural carbon and nutrient cycles, the role of coastal environment has been an important focal issue in the discussion about global environmental change [1]. Cai et al. [2] pointed out that coastal wetlands and salt marshes had been ignored in global carbon cycle research since inorganic carbon inputs from underground aquifers to the coastal zone may be a significant source of carbon to the coastal sea and atmosphere while Valiela and Teal [3], Johannes [4], and Moore [5] have highlighted the importance of carbon and nutrient transport via groundwater in some systems.The general characteristics of groundwater formed with the aid of atmospheric precipitation might show differences due to evapotranspiration, runoff, and seasonal changes of hydrological properties, size, and thickness of the vadose zone of the aquifer [6,7]. The change in the groundwater characteristics can be defined and evaluated by the geochemical evolution of dissolved organic carbon (DOC) as well as the dissolved nutrient balance. DOC is closely related to dissolved inorganic carbon (DIC), which is the sum of gaseous CO 2 , bicarbonate, and carbonate, and both are involved in important redox reactions taking place in hydro-geochemical processes [8,9]. DOC and particulate organic carbon (POC) comprises total organic carbon (TOC) in any given aqueous environment. DOC generally amounts to $90% of TOC in surface waters, whereas the DOC content in groundwater is generally below 1-2 mg C/L [7,10]. On the other hand, the nutrient content of any water resource is highly characterized by dissolved inorganic phosphate (DIP), inorganic nitrogen (DIN), and total alkalinity (TAlk) [11].Prior to this study, no records existed on the spatial or annual variability of total DOC, DIC, DIP, DIN, and TAlk of groundwater in Silifke plain, which is a RAMSAR site in Turkey. The purpose of this study was not only to investigate the present implications of the findings of the analytical results obtained but also to establish background data for much needed future monito...