1993
DOI: 10.1016/0921-4526(93)90531-a
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Ground state properties of UNi2Al3 and UPd2Al3

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Cited by 59 publications
(12 citation statements)
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“…Furthermore, such explanation appears in line with the picture that UNi 2 Al 3 has a more pronounced itinerant character than UPd 2 Al 3 . The stronger delocalization of the 5f electrons in UNi 2 Al 3 was notably inferred by the absence of a Curie-Weiss law in the susceptibility (see, for example, Geibel et al, 1993) and the nonobservation of Kondo-like behavior in the electrical resistivity. Hence the substitution of Ni for Pd, which is accompanied by a reduction of the unit-cell volume, increases the hybridization of the f electrons with the conduction electrons, driving the system away from a localized-moments behavior.…”
Section: Fig 19 Crystalline Structure Of Upd 2 Al 3 (And Uni 2 Al 3 )mentioning
confidence: 99%
“…Furthermore, such explanation appears in line with the picture that UNi 2 Al 3 has a more pronounced itinerant character than UPd 2 Al 3 . The stronger delocalization of the 5f electrons in UNi 2 Al 3 was notably inferred by the absence of a Curie-Weiss law in the susceptibility (see, for example, Geibel et al, 1993) and the nonobservation of Kondo-like behavior in the electrical resistivity. Hence the substitution of Ni for Pd, which is accompanied by a reduction of the unit-cell volume, increases the hybridization of the f electrons with the conduction electrons, driving the system away from a localized-moments behavior.…”
Section: Fig 19 Crystalline Structure Of Upd 2 Al 3 (And Uni 2 Al 3 )mentioning
confidence: 99%
“…Neutron scattering experiments (Geibel et al [176]) established the local moment in UPd2Al3 to be 0.85 B, while that in UNi2Al3 is (Schroeder et al [177]) is much smaller, 0.24 B. These were the first heavy fermion superconductors coexistent with a static local moment.…”
Section: Uni2al3 / Upd2al3mentioning
confidence: 99%
“…An important stimulation of interest in physics of the REPd 2 Al 3 compounds provided the discovery of the isostructural heavyfermion superconductors UPd 2 Al 3 ( = 150 mJ K −2 mol −1 , T SC = 2 K, T N = 14 K, and UNi 2 Al 3 [1][2][3]) where superconductivity coexists with quite large antiferromagnetically ordered U moments of 0.85 B (UPd 2 Al 3 ) [1]. All these 123 intermetallics adopt the same hexagonal PrNi 2 Al 3 -type crystal structure [4,5].…”
Section: Introductionmentioning
confidence: 99%