Articles you may be interested inA critical re-assignment of the Rydberg states of iodomethane based on new polarization data J. Chem. Phys. 138, 134308 (2013); 10.1063/1.4798972[1 + 1] photodissociation of CS 2 + ( X ̃ 2 Π g ) via the vibrationally mediated B ̃ 2 Σ u + state: Multichannels exhibiting and mode specific dynamicsThe k 3 ⌸ state of the CO molecule is investigated in the region between 91 000 and 97 000 cm Ϫ1 via 1ϩ1 resonance enhanced multiphoton ionization spectroscopy on CO molecules prepared in a single quantum level of the a 3 ⌸(vϭ1͒ state. A new vibronic band is found which is at lower energy than the vibrational ground state reported in the literature, leading to a reassignment of the vibrational numbering of the k 3 ⌸ state. The rotationally resolved spectra of the k 3 ⌸ (vϭ0-6͒ ←a 3 ⌸(vϭ1, Jϭ1, ⍀ϭ1͒ of 12 CO and 13 CO have been observed and analyzed, confirming the new vibrational labeling and providing a full set of molecular constants of the k 3 ⌸ valence state.