Ground state dissociation pathways for 3,4,-dichloro-1,2,5-thiadiazole: Spectroscopic observation and fate of NC C(Cl2) N S isomer

Dissociation pathways for the molecular cation of 3,4‐dichloro‐1,2,5‐thiadiazole: A time‐of‐flight mass spectrometry and computational study

“…These results were also supported using chemical ionization and vacuum pyrolysis experiments . Recently, we have studied the photodissociation dynamics of 3,4‐dichloro‐1,2,5‐thiadiazole in its excited and ground state using various techniques such as resonance enhanced multiphoton ionization (REMPI) detection of Cl atom, UV absorption and emission spectroscopy …”

“…[12,13] Recently, we have studied the photodissociation dynamics of 3,4-dichloro-1,2,5-thiadiazole in its excited and ground state using various techniques such as resonance enhanced multiphoton ionization (REMPI) detection of Cl atom, UV absorption and emission spectroscopy. [14,15] In addition to the spectroscopic and photochemical studies, this class of compound has received attention recently due to their use as the starting materials for the various reactive nitrile sulfide intermediates in photochemical synthesis and preparative chemistry. [16] Several studies have been initiated using these thiadiazoles due to their potential use as insecticides, herbicides and various drugs.…”