A novel solid acid
nanocatalyst (Ag1(NH4)2PW12O40/UiO-66) comprising ammonium
and silver co-doped H3PW12O40 and
zirconium-based metal–organic frameworks (UiO-66) was synthesized
and characterized by Fourier transform infrared spectroscopy, N2 adsorption/desorption, X-ray diffraction, scanning electron
microscopy, transmission electron microscopy, thermogravimetric analysis,
and ammonia temperature-programmed desorption. The catalytic activity
was evaluated for the synthesis of biodiesel via esterification of
lauric acid and methanol. The effect of the operating parameters including
the molar ratio of lauric acid to methanol, catalyst amount, and reaction
temperature and time on the lauric acid conversion was also investigated
to obtain optimum reaction conditions. Also, the composite (Ag1(NH4)2PW12O40/UiO-66)
was recyclable and reused up to six cycles. Kinetics of the lauric
acid esterification has been assumed to be of a pseudo-first order,
and the results showed that the activation energy for the esterification
process was found to be 35.2 kJ/mol.