Green synthesis of mesoporous molecular sieve incorporated monoliths using room temperature ionic liquid and deep eutectic solvents

Zhang, Li-Shun; Zhao, Qing‐Li; Li, Xinxin; Li, Xixi; Huang, Yanping; Liu, Zhao‐Sheng

doi:10.1016/j.talanta.2016.09.030

Cited by 25 publications

(10 citation statements)

References 33 publications

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“…These monoliths were used for solid-phase microextraction (SPME) and separation of the non-steroidal anti-inflammatory drugs ketoprofen, flurbiprofen and diclofenac sodium from aqueous solution. The group of Liu has also reported the use of ChCl:propylene glycol DES systems (in conjunction with room temperature ILs) as porogens for the development of poly(butyl methacrylate-co-ethylene glycol dimethacrylate) monoliths with incorporated carbon nanotubes [115] or MCM-41 molecular sieves [116]. Carbon nanotubes were able to be successfully dispersed into the pre-polymerization mixture without oxidative cutting and with no observed precipitation.…”

Section: Synthesis Via Porogensmentioning

confidence: 99%

Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science

Nahar

Thickett

2021

Polymers

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Deep eutectic solvents (DESs) represent an emergent class of green designer solvents that find numerous applications in different aspects of chemical synthesis. A particularly appealing aspect of DES systems is their simplicity of preparation, combined with inexpensive, readily available starting materials to yield solvents with appealing properties (negligible volatility, non-flammability and high solvation capacity). In the context of polymer science, DES systems not only offer an appealing route towards replacing hazardous volatile organic solvents (VOCs), but can serve multiple roles including those of solvent, monomer and templating agent—so called “polymerizable eutectics.” In this review, we look at DES systems and polymerizable eutectics and their application in polymer materials synthesis, including various mechanisms of polymer formation, hydrogel design, porous monoliths, and molecularly imprinted polymers. We provide a comparative study of these systems alongside traditional synthetic approaches, highlighting not only the benefit of replacing VOCs from the perspective of environmental sustainability, but also the materials advantage with respect to mechanical and thermal properties of the polymers formed.

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Section: Synthesis Via Porogensmentioning

confidence: 99%

Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science

Nahar

Thickett

2021

Polymers

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“…31,32 For solving the problem of viscosity, researchers have combined ILs with a porous material to form a solid adsorbent for NH 3 capture. [33][34][35][36][37][38][39][40] Zeng et al 35 supported three metal ionic liquids (MILs) with a good affinity for NH 3 onto SG to prepare new MIL/SG adsorbents. Among them, the [Bmim] 2 [Co(NCS) 4 ]/SG composite not only exhibits much higher NH 3 capacity and selectivity than the original SG but also shows a faster adsorption rate and excellent reversibility than the corresponding MILs.…”

Section: Introductionmentioning

confidence: 99%

Highly efficient and reversible adsorption of ammonia by incorporation of deep eutectic solvents into silica gel and Al₂O₃

Zong

Zhou

et al. 2022

New J. Chem.

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“…40,41 In addition, good hydrophilicity of DESs can significantly improve the adsorption capacity of hydrophilic targets. 36,42 zinc acrylate (ZnA) can form a strong metal covalent interaction and a steady five-membered ring with the template in metal-chelating imprinting. The selection of functional monomers during MIP polymerization may affect its imprinting performance.…”

Section: Introductionmentioning

confidence: 99%

Improving the Identification of Lysine-Acetylated Peptides Using a Molecularly Imprinted Monolith Prepared by a Deep Eutectic Solvent Monomer

et al. 2022

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To overcome the identification challenge of low-abundance lysine acetylation (Kac), a novel approach based on a molecularly imprinted polymer (MIP) was developed to improve the extraction capacity of Kac peptides in real samples. Green deep eutectic solvents (DESs) were introduced and used as one of the synergistic functional monomers with zinc acrylate (ZnA). Glycine–glycine–alanine–lysine(ac)–arginine (GGAKacR) was chosen as a template and N,N′-methylenbisacrylamide (MBAA) was used as a cross-linker. The obtained GGAKacR-MIP had excellent selectivity for the template with an imprinting factor (IF) of up to 21.4. The histone digest addition experiment demonstrated that GGAKacR-MIP could successfully extract GGAKacR from a complex sample. Finally, the application to the extraction of Kac peptides from mouse liver protein digestion was studied in detail. The number of Kac peptides and Kac proteins identified was 130 and 110, which were 3.71-fold and 3.93-fold higher than those of the untreated sample. In addition, the number of peptides and proteins identified after treatment increased from 5535 and 1092 to 17 149 and 4037 (3.10-fold and 3.70-fold, respectively). The results showed that the obtained MIP may provide an effective technical tool for the identification of Kac-modification and peptide fractionation, as well as a potential approach for simultaneously identifying post-translational-modified proteomic and proteomic information.

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Green synthesis of mesoporous molecular sieve incorporated monoliths using room temperature ionic liquid and deep eutectic solvents

Cited by 25 publications

References 33 publications

Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science

Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science

Highly efficient and reversible adsorption of ammonia by incorporation of deep eutectic solvents into silica gel and Al₂O₃

Improving the Identification of Lysine-Acetylated Peptides Using a Molecularly Imprinted Monolith Prepared by a Deep Eutectic Solvent Monomer

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Green synthesis of mesoporous molecular sieve incorporated monoliths using room temperature ionic liquid and deep eutectic solvents

Cited by 25 publications

References 33 publications

Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science

Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science

Highly efficient and reversible adsorption of ammonia by incorporation of deep eutectic solvents into silica gel and Al2O3

Improving the Identification of Lysine-Acetylated Peptides Using a Molecularly Imprinted Monolith Prepared by a Deep Eutectic Solvent Monomer

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Highly efficient and reversible adsorption of ammonia by incorporation of deep eutectic solvents into silica gel and Al₂O₃