Green Production of Anionic Surfactant Obtained from Pea Protein

Rondel, Caroline; Portet, Bénédicte; Alric, Isabelle; Mouloungui, Zéphirin; Blanco, Jean‐François; Silvestre, Françoise

doi:10.1007/s11743-011-1283-2

Cited by 19 publications

(18 citation statements)

References 36 publications

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“…For example, chemical modifications such as phosphorylation through dry heating in the presence of pyrophosphate (Hayashi et al, 2009), acylation (Rondel et al, 2011), acetylation and succinylation (Lin & Chen, 2006;Lin & Chen, 0000) Review on industrial chemicals, materials and energy 7…”

Section: Conversion Into Surfactants and Firefighting Foamsmentioning

confidence: 99%

Valorization of rendering industry wastes and co-products for industrial chemicals, materials and energy: review

Mekonnen

Mussone

Bressler

2015

Critical Reviews in Biotechnology

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Over the past decades, strong global demand for industrial chemicals, raw materials and energy has been driven by rapid industrialization and population growth across the world. In this context, long-term environmental sustainability demands the development of sustainable strategies of resource utilization. The agricultural sector is a major source of underutilized or low-value streams that accompany the production of food and other biomass commodities. Animal agriculture in particular constitutes a substantial portion of the overall agricultural sector, with wastes being generated along the supply chain of slaughtering, handling, catering and rendering. The recent emergence of bovine spongiform encephalopathy (BSE) resulted in the elimination of most of the traditional uses of rendered animal meals such as blood meal, meat and bone meal (MBM) as animal feed with significant economic losses for the entire sector. The focus of this review is on the valorization progress achieved on converting protein feedstock into bio-based plastics, flocculants, surfactants and adhesives. The utilization of other rendering streams such as fat and ash rich biomass for the production of renewable fuels, solvents, drop-in chemicals, minerals and fertilizers is also critically reviewed.

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Section: Conversion Into Surfactants and Firefighting Foamsmentioning

confidence: 99%

Valorization of rendering industry wastes and co-products for industrial chemicals, materials and energy: review

Mekonnen

Mussone

Bressler

2015

Critical Reviews in Biotechnology

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“…Foaming properties of surfactants prepared from peptides obtained by the enzymatic hydrolysis of rapeseed were found to be better for C12-than for C10-acylated derivatives [33]. Similarly, for anionic surfactants obtained from pea protein, the best foaming capacity was also reported for the C12-acylated mixture [34].…”

Section: Foaming Propertiesmentioning

confidence: 81%

Valorization of tannery wastes: Lipoamino acid surfactant mixtures from the protein fraction of process wastewater

Bautista

Pérez

Garcı́a

et al. 2015

Chemical Engineering Journal

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The first stages of the transformation process of hides into leather (beamhouse process) generate an important waste in the tanning industry, since a considerable fraction of solubilised proteins ends up in waste water with the corresponding increase in contamination parameters, especially when the process is carried out without hair recovery (hair-pulping process). The objective of this work was the valorisation of this waste (the separated protein fraction) which conveniently hydrolyzed to amino acid level constituted the starting material for the production of biodegradable surfactants.The lipoamino acid surfactants were obtained by acylation of the amino acids from the protein hydrolisate. These surfactants were characterized and their physico-chemical and biological properties evaluated. They exhibit very low cmc values (about 40 mg/L).These surfactants are readily biodegradable and present an aquatic toxicity significantly lower than many common commercial surfactants derived whether from renewable or petrochemical feedstock. The mixtures of surfactants obtained are able to form oil/water emulsions that remain stable for at least one year. The results obtained in this work confirmed that it is possible the production of biodegradable and efficient lipoamino acid surfactant mixtures from the protein fraction present in beamhouse process wastewaters. This study constitutes a promising approach for the reduction of the pollution load from industrial tannery wastes and its valorisation as raw material for the production of surfactants with excellent environmental properties and good technical properties.

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“…Therefore, the focus on finding natural and nontoxic types of corrosion inhibitors is considered desirable and of great importance. Some conventional surfactants have been replaced by surfactants derived from natural oils such as cashew nut shell oil [14], Gliricidia sepium [15], pea protein [16], and vegetable oil [17]. These surfactants are characterized by their extreme tendency towards biodegradation, which means the degradation of organic compounds using microorganisms to produce compounds of low molecular weight, such as alcohols and short-chain fatty acids.…”

Section: Introductionmentioning

confidence: 99%

Vanillin-derived non-ionic surfactants as green corrosion inhibitors for carbon steel in acidic environments

Tawfik

Negm

2015

Res Chem Intermed

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Four eco-friendly ('green') non-ionic surface active agents were synthesized via reaction of fatty acids obtained from hydrolysis of castor oil with vanillin. The products were then reacted with monoethanol amine to form a vanillin ester Schiff base. The vanillin ester Schiff base was ethoxylated using ethylene oxide gas in the presence of tri-ethyl amine as a catalyst to give the desired nonionic surfactants. The chemical structures of the obtained surfactants were characterized using FTIR and 1 HNMR spectroscopy. The inhibition effect of the four synthesized non-ionic surfactants derived from vanillin (VE15, VE20, VE40, and VE60) on the corrosion of carbon steel in acidic media of 0.5-M HCl was studied by weight loss, potentiodynamic and electrochemical impedance spectroscopy measurements. The results show that the synthesized inhibitors are effective inhibitors even at very low concentrations, and the adsorption on carbon steel surface obeys the Langmuir adsorption isotherm. Potentiodynamic polarization curves reveal that the synthesized inhibitors behave as mixed-type inhibitors. Adsorption of used inhibitors led to a reduction in the double layer capacitance and an increase in the charge transfer resistance. Calculated DG ads o values indicated that the mechanism by which these inhibitors adsorb onto carbon steel in 0.5-M HCl solution is chemical adsorption. The surface activities of the synthesized surfactants were determined using surface tension measurements. The biodegradability of these surfactants indicates that the compounds readily degrade in the environment and can be considered as green corrosion inhibitors.

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Green Production of Anionic Surfactant Obtained from Pea Protein

Abstract: To link to this article: DOI:10.1007/S11743-011-1283-

Cited by 19 publications

References 36 publications

Valorization of rendering industry wastes and co-products for industrial chemicals, materials and energy: review

Valorization of rendering industry wastes and co-products for industrial chemicals, materials and energy: review

Valorization of tannery wastes: Lipoamino acid surfactant mixtures from the protein fraction of process wastewater

Vanillin-derived non-ionic surfactants as green corrosion inhibitors for carbon steel in acidic environments

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