Abstract:The key pathways for synthesizing nanoparticles are physical and chemical, usually expensive and possibly hazardous to the environment. In the recent past, the evaluation of green chemistry or biological techniques for synthesizing metal nanoparticles from plant extracts has drawn the attention of many researchers. The literature on the green production of nanoparticles using various metals (i.e., gold, silver, zinc, titanium and palladium) and plant extracts is discussed in this study. The generalized mechani… Show more
“…Analyses of the composition of Echinacea extracts revealed that chicoric acid was the dominant component (among the phenylpropanoids) [ 13 ], along with phenolic compounds such as flavonoids [ 14 ], tannins, alkaloids, starch, furochromones, and glycosides [ 15 ], all of them acting as reducing agents and stabilizing agents in the synthesis of nanoparticles [ 16 ].…”
With their phytoconstituents acting as reducing and capping agents, natural extracts can be considered a viable alternative for the obtaining of metallic nanoparticles. The properties of phytosynthesized nanoparticles are dependent upon size and morphology, which, in turn, can be tailored by adjusting different parameters of the phytosynthesis process (such as the extracts’ composition). In the present study, we aimed to evaluate, for the first time in the literature, the influence of the extraction method and extract concentration on the morphological and biological properties (antioxidant and antibacterial activity) of silver nanoparticles phytosynthesized using Echinacea pupurea L. extracts. The obtained results revealed that the use of the low-concentration Echinacea hydro-alcoholic extract obtained via classical temperature extraction led to the development of nanoparticles with the smallest dimensions (less than 10 nm), compared with the use of extracts obtained with higher concentrations and the extract obtained via the microwave method. The developed nanomaterials exhibited enhanced antioxidant effects (determined via the DPPH assay) and antimicrobial properties (against Escherichia coli and Candida albicans), compared with the parent extracts.
“…Analyses of the composition of Echinacea extracts revealed that chicoric acid was the dominant component (among the phenylpropanoids) [ 13 ], along with phenolic compounds such as flavonoids [ 14 ], tannins, alkaloids, starch, furochromones, and glycosides [ 15 ], all of them acting as reducing agents and stabilizing agents in the synthesis of nanoparticles [ 16 ].…”
With their phytoconstituents acting as reducing and capping agents, natural extracts can be considered a viable alternative for the obtaining of metallic nanoparticles. The properties of phytosynthesized nanoparticles are dependent upon size and morphology, which, in turn, can be tailored by adjusting different parameters of the phytosynthesis process (such as the extracts’ composition). In the present study, we aimed to evaluate, for the first time in the literature, the influence of the extraction method and extract concentration on the morphological and biological properties (antioxidant and antibacterial activity) of silver nanoparticles phytosynthesized using Echinacea pupurea L. extracts. The obtained results revealed that the use of the low-concentration Echinacea hydro-alcoholic extract obtained via classical temperature extraction led to the development of nanoparticles with the smallest dimensions (less than 10 nm), compared with the use of extracts obtained with higher concentrations and the extract obtained via the microwave method. The developed nanomaterials exhibited enhanced antioxidant effects (determined via the DPPH assay) and antimicrobial properties (against Escherichia coli and Candida albicans), compared with the parent extracts.
“…Generally, in the process of synthesizing metal nanoparticles by reduction method, the length of reaction time will affect the synthesis amount and particle size distribution of metal nanoparticles ( Khan, et al, 2022 ). After determining the optimal reaction pH and temperature for synthesizing GO-AgNPs using GA at 9 and 45°C, in order to explore the effect of reaction time on the number and morphology of AgNPs in GO-AgNPs.…”
The adoption of plant-derived natural products to synthesize metal nanoparticles and their complexes has the advantages of mild reaction conditions, environmental protection, sustainability and simple operation compared with traditional physical or chemical synthesis methods. Herein, silver nanoparticles (AgNPs) were in situ synthesized on the surface of graphene oxide (GO) by a “one-pot reaction” to prepare graphene oxide-silver nanoparticles composite (GO-AgNPs) based on using AgNO3 as the precursor of AgNPs and gallic acid (GA) as the reducing agent and stabilizer. The size and morphology of GO-AgNPs were characterized by ultraviolet-visible spectrophotometer (Uv-vis), Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope (TEM), X-ray diffractometer (XRD) and dynamic light scattering (DLS). The effects of pH, temperature, time and material ratio on the synthesis of GO-AgNPs were investigated experimentally. The results showed that ideal GO-AgNPs could be prepared under the conditions of pH = 9, 45°C, 2 h and the 2:1 of molar ratio of AgNO3 to GA. The AgNPs within GO-AgNPs are highly crystalline spherical particles with moderate density on the surface of GO, and the size of AgNPs is relatively uniform and determined to be about 8.19 ± 4.21 nm. The research results will provide new ideas and references for the green synthesis of metal nanoparticles and their complexes using plant-derived natural products as the reducing agent and stabilizer.
“…It is widely used in some catalytic reactions, [1] such as the photocatalytic production of hydrogen [2] and molecular Oxygen Promotes Hydrogen Production from formaldehyde Solution [3] . Unfortunately, agglomeration tends to occur due to the high surface energy of AgNPs [4–6] . Therefore, it is challenging to obtain uniformly distributed AgNPs materials, and a suitable carrier is usually chosen as the substrate material for AgNPs.…”
Section: Introductionmentioning
confidence: 99%
“…[3] Unfortunately, agglomeration tends to occur due to the high surface energy of AgNPs. [4][5][6] Therefore, it is challenging to obtain uniformly distributed AgNPs materials, and a suitable carrier is usually chosen as the substrate material for AgNPs.…”
Silver nanoparticles (AgNPs) was loaded on spherical celluloseimmobilized tannin resin (CC-TA) with AgNO 3 solution as the silver source, where CC-TA was prepared by the cross-linking polymerization of tannin-based pre-polymer and cellulose. The tannin introduced onto the cellulose backbone was used as a reduction reagent for silver ions and a stabilizing agent for AgNPs. The AgNPs are uniform, and the average size is about 6.44 � 3.19 nm. The catalytic activity of AgNPs supported on cellulose-immobilized tannin resin(CC-TA@AgNPs)was detected by the reaction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP). This reaction could be accomplished within 1.5 min with an apparent rate constant of 2.32 min À 1 . The CC-TA@AgNPs has good cycle catalytic performance, and the conversion rate of 4-NP to 4-AP in the presence of CC-TA@AgNPs is about 100 % after five consecutive cycles. Therefore, the CC-TA@AgNPs is expected to be a promising catalytic material.
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