A novel core–shell nanomaterial, ZnO@SiO2, based
on rice husk for antibiotic and bacteria removal, was successfully
fabricated. The ZnO@SiO2 nanoparticles were characterized
by X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX),
Fourier transform infrared (FTIR) spectroscopy, transmission electron
microscopy (TEM), photoluminescence spectroscopy (PL), Brunauer–Emmett–Teller
(BET) method, diffuse reflectance ultraviolet–vis (DR-UV–vis)
spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy,
and ζ-potential measurements. β-Lactam antibiotic amoxicillin
(AMX) was removed using ZnO@SiO2 nanoparticles with an
efficiency greater than 90%, while Escherichia coli removal was higher than 91%. The optimum effective conditions for
AMX removal using ZnO@SiO2, including solution pH, adsorption
time, and ZnO@SiO2 dosage, were 8, 90 min, and 25 mg/mL,
respectively. The maximum adsorption capacity reached 52.1 mg/g, much
higher than those for other adsorbents. Adsorption isotherms of AMX
on ZnO@SiO2 were more in accordance with the Freundlich
model than the Langmuir model. The electrostatic attraction between
negative species of AMX and the positively charged ZnO@SiO2 surface induced adsorption, while the removal of E. coli was governed by both electrostatic and hydrophobic
interactions. Our study demonstrates that ZnO@SiO2 based
on rice husk is a useful core–shell nanomaterial for antibiotic
and bacteria removal from water.