Green Coffee Bean Extract Assisted Facile Synthesis of Reduced Graphene Oxide and Its Dye Removal Activity

Abstract

To discharge the colored effluents from industries there needs to be effective and affordable treatment options. Adsorption using reduced graphene oxide (rGO) as an adsorbent is a prominent one. In this study, green coffee bean extract (GCBE) is utilized as a safe reducing agent for the reduction of graphene oxide (GO) to synthesize rGO. The formation of rGO is confirmed by a new peak in the UV–vis spectra at 275 nm and a diffraction peak in the XRD patterns at 22°. The effective formation of rGO is further substantiated by a change in the GO peak's properties in the FTIR, EDX, and Raman spectra and a weight loss change in TGA. The SEM and TEM analyses demonstrate the effective production of the nano‐sheets of rGO having exfoliated and segregated in a few layers. Furthermore, the obtained rGO exhibited outstanding efficacy in wastewater cleanup, effectively adsorbing MB as a prototype organic dye. The kinetics and isotherm study suggested that the adsorption leads by the chemisorption and monolayer formation on the homogeneous surface of rGO. The maximum adsorption capacity is found to be 89.3 mg g−1. This process offers a fresh opportunity for the economical and safe production of rGO for wastewater treatment.

Piper chaba Stem Extract Facilitated the Synthesis of Iron Oxide Nanoparticles as an Adsorbent to Remove Congo Red Dye

“…The kinetics of adsorption is a crucial component in determining its efficacy. Various kinetic models have been offered by different researchers. − Three important kinetic models were employed in the current investigation, namely, pseudo-first-order, pseudo-second-order, and intraparticle diffusion (IPD) kinetic models. The time-dependent adsorption of CR was performed at pH 4 using 20 mg/L CR and 20 mg of IONPs in 0.1 L volume.…”

“…The relationship between the amount of adsorbate absorbed per unit weight of adsorbent ( q e , mg g –1 ) and the adsorbate concentrations in the bulk solution ( C e , mg L –1 ) was investigated using adsorption isotherms. ,, The Langmuir, Freundlich, and Temkin adsorption models, which are frequently used to explain how organic dyes adsorb onto various adsorbents, have been employed, among other adsorption isotherm models. ,,,− The adsorption isotherms of CR onto the surface of IONPs are shown in Figure , and the resulting data are presented in Table . The weight concentration of IONPs (5–40 mg in 100 mL) and the measurements were carried out at a pH value of 4 for which adsorption is the most efficient.…”

“… 50 , 54 , 57 The Langmuir, Freundlich, and Temkin adsorption models, which are frequently used to explain how organic dyes adsorb onto various adsorbents, have been employed, among other adsorption isotherm models. 29 , 50 , 52 , 57 − 59 The adsorption isotherms of CR onto the surface of IONPs are shown in Figure 12 , and the resulting data are presented in Table 2 . The weight concentration of IONPs (5–40 mg in 100 mL) and the measurements were carried out at a pH value of 4 for which adsorption is the most efficient.…”