2019
DOI: 10.1016/j.carbon.2019.04.104
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Graphitic carbon nitride (g–C3N4)–based metal-free photocatalysts for water splitting: A review

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Cited by 653 publications
(215 citation statements)
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“…The strategy of the process mainly depends on the movement of electrons from the valence band (VB) to the conduction band (CB) on a surface of the semiconductor metal oxide nanoparticles by illumination with a suitable wavelength of light. These created excitons react with oxygen or water to produce superoxide anions and hydroxyl radicals as a reactive oxygen species (ROS) [14,15]. These species possess the great oxidizing potential to destruct several types of materials including industrial organic dyes.…”
Section: Introductionmentioning
confidence: 99%
“…The strategy of the process mainly depends on the movement of electrons from the valence band (VB) to the conduction band (CB) on a surface of the semiconductor metal oxide nanoparticles by illumination with a suitable wavelength of light. These created excitons react with oxygen or water to produce superoxide anions and hydroxyl radicals as a reactive oxygen species (ROS) [14,15]. These species possess the great oxidizing potential to destruct several types of materials including industrial organic dyes.…”
Section: Introductionmentioning
confidence: 99%
“…2 It is an organic semiconductor composed of carbon and nitrogen in a layered structure made of graphene-like extended sheets with gentle layer undulations. 3 Graphitic carbon nitride has attracted increased attention during the last decade, [4][5][6][7] since the report in 2009 of its application as a visible light photocatalyst for hydrogen evolution from water. 8 Photocatalytic hydrogen production is regarded as a very promising approach to generate clean fuels, as a possible replacement to fossil fuels which have well-known problems of carbon emissions, limited supply, high extraction costs and supply chain volatility.…”
Section: Introductionmentioning
confidence: 99%
“…[ 3–5 ] However, owing to its narrow spectral absorption (the bandgap is ≈2.7 eV), high recombination of photocarriers (due to its slow holes transfer rate) and sluggish interfacial kinetics for O 2 production, the application of pure g‐C 3 N 4 as a photoanode for water oxidation has still remained a challenge. [ 4,6,7 ] Recently, construction heterojunction [ 8–10 ] with a secondary semiconductor such as TiO 2 , [ 11 ] SnO 2 , [ 12 ] CdS, [ 13 ] and BiVO 4 [ 14,15 ] is an effective strategy to improve the performance of g‐C 3 N 4 based photoanodes. Although the success has been achieved from the above heterojunctions, their stabilities were still not well controllable.…”
Section: Introductionmentioning
confidence: 99%