2013
DOI: 10.3144/expresspolymlett.2013.29
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Graphene reinforced biodegradable poly(3-hydroxybutyrate-co-4-hydroxybutyrate) nano-composites

Abstract: Novel biodegradable poly(3-hydroxybutyrate-co-4-hydroxybutyrate) [PHBV]/graphene nanocomposites were prepared by solution casting. The thermal properties, crystallization behavior, microstructure, and fracture morphology of the composites were investigated. Scanning electron microscope (SEM) results show that graphene layers are homogeneously dispersed in the polymer matrix. X-ray diffraction (XRD) and dynamic scanning calorimetry (DSC) studies show that the well dispersed graphene sheets act as nucleating age… Show more

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Cited by 118 publications
(93 citation statements)
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“…This can be attributed to two reasons. Firstly, the filler effect mentioned earlier, namely filler can act as physical interlock points, which confine polymer chains and reduce the chains mobility [40]. Secondly, the LC domains also act as crosslink, tying segments of the polymer chain together [19].…”
Section: Resultsmentioning
confidence: 99%
“…This can be attributed to two reasons. Firstly, the filler effect mentioned earlier, namely filler can act as physical interlock points, which confine polymer chains and reduce the chains mobility [40]. Secondly, the LC domains also act as crosslink, tying segments of the polymer chain together [19].…”
Section: Resultsmentioning
confidence: 99%
“…In addition, graphene, a new generation carbonaceous-layered material has shown considerable potential as a reinforcing material in polymer nanocomposites. It has a very large surface area and tunable surface properties [109][110][111][112][113][114].…”
Section: Future Challenges and Conclusion Remarksmentioning
confidence: 99%
“…Natural rubber, the solid form of creamy latex from the heveabrasiliensis tree, is one of the selected materials [1]. The majorcomposition is composed of cis-poly (isoprene)-isoprene monomer.…”
Section: Introductionmentioning
confidence: 99%
“…A bioplastic-based material of polyhydroxybutyrate-cohydroxyvalerate (PHBV) is a member of the polyhydroxylalkanoates (PHAs) which are produced by microbial activity on sugar-based system [1][2][3]. This biopolymer is presented itself as the biodegradable polymer and aliphatic polyesters because of naturally synthesized materials from renewable supplies.…”
Section: Introductionmentioning
confidence: 99%