The interactions of composition, microstructure, and corrosion processes have been studied extensively. In stress-corrosion cracking (SeC)-where mechanical stresses can accelerate failure-material chemistry and microstructure can alter the corrosion attack as well as influence deformation and fracture. The mechanisms through which these effects are felt, however,do not apply universally and are often difficult to elucidate. This article reviews mechanisms wherein corrosion behavior is the main influence, examining how segregation and precipitation at grain boundaries affects intergranular Sec.