The geometry and composition of deformation-related low-angle boundaries in naturally-10 deformed olivine were characterized by electron backscattered diffraction (EBSD) and atom probe 11 tomography (APT). EBSD data show the presence of discrete low-angle tilt boundaries, which formed 12 by sub-grain rotation recrystallisation associated with the (100)[001] slip system during fluid-13 catalysed metamorphism and deformation. APT analyses of these interfaces show the preferential 14 segregation of olivine-derived trace elements (Ca, Al, Ti, P, Mn, Na and Co) to the low-angle 15 boundaries. Boundaries with < 2° show marked enrichment associated with the presence of multiple, 16 non-parallel dislocation types. However, at larger disorientation angles (> 2°), the interfaces become 17 more ordered and linear enrichment of trace elements coincides with the orientation of dislocations 18 inferred from the EBSD data. These boundaries show a systematic increase of trace element 19 concentration with disorientation angle. Olivine-derived trace elements segregated to the low-angle 20 boundaries are interpreted to be captured and travel with dislocation as they migrate to the sub-grain 21 boundary interfaces. However, the presence of exotic trace elements Cl and H, also enriched in the 22 low-angle boundaries, likely reflect the contribution of an external fluid source during the fluid-23